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The Effect of Hydrogen Bonding on the Nucleophilicity and Basicity of Fluorid...
In nucleophilic fluorination reactions it is extremely difficult to tune the reactivity of the fluoride anion in organic solution to give the desired product. Building on our... -
Heterolytic Cleavage of H2 using Non-Metal Frustrated Lewis Pairs
The synthesis of Frustrated Lewis Pairs (FLP¿s) have recently experienced a huge surge in popularity as they have been found to be a novel approach for the activation of small... -
Crystal structure of Lu5Rh6Sn18 and Y5Rh6Sn18
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Neutron Diffraction Studies on YbCu4Ga8
We discovered a new compound YbCu4Ga8 and the available laboratory single crystal data shows that it crystallizes in the tetragonal system. The asymmetric unit contains one Yb... -
Characterising anion binding by analysis of the electron density distribution
The aim of our work is to use charge density analysis to gain insight into the process of binding relatively small anions by specifically designed small organic molecules. These... -
Investigating the origin of thermochromism in N-salicylideneanilines
Anils, N-salicylideneanilines, display thermochromism, which is thought to involve an intramolecular proton shift, but to-date the structural changes postulated to occur during... -
Multitemperature measurements of 2,6-diaminopurine monohydrate crystals
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Short range order in ferroelectric deuterated triglycine sulphate
We want to better understand the structural modifications and short-range correlations in ferroelectric triglycine sulphate near the ferroelectric phase transition. Above the... -
Short range spin ice type correlations of HoAgGe by diffuse neutron scattering
Spin ices are exotic phases of matter characterized by frustrated spins obeying local ice rules that minimize the number of spatially isolated magnetic monopoles, in analogy... -
Magnetism and structural diffuse scattering in α-CoV3O8:
We propose to measure the magnetic structure and diffuse scattering in a Vanadium Bronze material α-CoV3O8. These materials are of interest due to possible applications for... -
Crystal structure of Kondo insulator single crystal CeRu2Al9.9Si0.1
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Sinergic Raman and neutron diffraction measurements on SXD
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CPRO#1 T=300K wtl=10.0 j:14,14
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Reversible B-H Bond Activation at Cationic Rh(III) Centres: Structural Charac...
Catalytic processes leading to the functionalization of organic molecules by boron-containing reagents are highly topical ¿ ranging from transition metal catalysed hydro- and... -
Nature of Disorder in Relaxor-like Ferroelectric AB(HCO2)3 Frameworks
Relaxor ferroelectics are of significant interest for use as piezoelectric actuators in sensing applications and for high precision mechanical stages. Relaxors are traditionally... -
Two-Dimensional Incommensurate Modulation in Melilite
We have prepared large single crystals of the melilite electroltyes Ln1+xCaxGa3O7+d; (Ln = La and Nd; x = 0 and 0.5) using a floating zone mirror furnace. We have characterised... -
Probing the ground state magnetic structure of single crystalline Ho3Fe5O12, ...
Lu and Ho counterparts of RE3Fe5O12 will be an appropriate platform to reveal the complexmagnetic ground state of rare earth iron garnets with common formula RE3Fe5O12. Lu3+... -
Magnetic structure of Sr2CoO2Cu2Se2
We will use single crystal neutron diffraction to determine the magnetic structure of the Co2+ moments in the layered oxide chalcogenide Sr2CoO2Cu2Se2. This will enable us to... -
Vibrational frequencies of light-induced photoisomers for optical data storag...
Ruthenium-based SO2 complexes present attractive prospects for next-generation 3-D optical data storage. Light is absorbed by the SO2 group, causing its dark state geometry (0)... -
crystal structure of potential new spin liquid
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