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Structure-property relationships in new oxide ion conductor Ba3NbWO8.5
Oxide ion conductors have been a focus of intense research due to their application as electrolytes in solid oxide fuel cells. The currently used materials (yttria-stabilised... -
Single Crystal Investigations of Polymorphism and Disorder in CH3NH3PbI3
Photovoltaics are one of the most promising technologies for meeting future energy requirements. CH3NH3PbI3 was first used in a solar cell in 2009, which gave an efficiency of... -
Crystal structure of novel transparent conducting oxides
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Inelastic scattering from zinc oxide by neutron Laue diffraction
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Spin excitations in overdoped BaFe1.2Ru0.8As2 (Tc=10 K)
Overdoped BaFe1.2Ru0.8As2 is an ideal system for comparison study between band structure calculation and spin excitation spectrum, because the electron correlation is expected... -
The charge-ordered superstructure of YbFe2O4
There has been much recent interest in the so-called ¿novel¿ or ¿type-II¿ multiferroics, in which electrical polarisation appears at the onset of a particular type of magnetic... -
Crystal chemistry of Ca2B6O6(OH)10•2H2O
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Do defect structures in the pyrochlore Tb2Ti2O7 control hidden order or the t...
The rare earth pyrochlores have been at the forefront of research into exotic magnetic phenomena for some years. In general they are of interest because they are frustrated -... -
Thermochromism in N-salicylideneanilines
N-salicylidineanilines are known to show thermochromic behaviour, which is currently postulated to arise from an intramolecular proton shift between the keto and enol form as... -
Atomic resolution holographic study of polycrystalline yttrium hydride
It is commonly accepted that the recording of holograms with atomic resolution requires singlecrystalline samples. Closer analysis, however, shows that the reduced information... -
Diffuse scattering study of single crystal PrBa2Cu3O7-x
Standard diffraction studies of PrBCO and YBCO show that these two compounds are isostructical. However, if any Pr/Ba disorder is present in PrBCO, the diffuse scattering signal... -
Defects and spin correlations in yttrium-doped spin ice
Excitations in spin ice fractionalize into de-confined magnetic monopoles that interact with each other via the magnetic Coulomb interaction. Substituting rare earth ions with... -
Magnetic Structure and Martensite Twin-Laws of ferromagnetic Co2-Ni-Ga and Fe...
Pseudoelastic, ferromagnetic Co2NiGa type high-temperature shape memory alloys (HT-SMAs) are characterized by a wide range of tunable transformation temperatures and lower... -
Determination of the Crystallographic and Magnetic structures of RbMnBr3, RbF...
We propose to study the crystal structures of RbMnBr3, RbFeBr3 and RbNiBr3 between 300 and 0.3 K. RbMnBr3 under goes two structural phase transition by reducing Rb coordination.... -
Defect structure of oxygen-deficient Yb2Zr2O6.5
Ytterbium zirconate is of fundamental interest as a model frustrated magnet, and of potential technological importance as a thermal barrier material. In both cases oxygen... -
High-energy excitations in charge and orbital ordered La0.5Sr1.5MnO4
The colossal magnetoresistance effect in manganites arises from a competition between delocalisation, which favours a ferromagnetic metallic phase, and localisation of electons... -
Single-Crystal Neutron Diffraction Study on [U(C5Me5)2(H)(mu¿H)]2
To our knowledge, the length of the U¿H single bond has never been accurately measured, at least not in a molecular compound by single-crystal neutron diffraction. We currently... -
Influence of superstructures on rich transport properties of lithium cobaltate
In the vicinity of x ~ 0.75, LixCoO2 has potential as a thermoelectric, since it has a high Seebeck coefficient and metallic conductivity. We have performed the first successful... -
Single-crystal neutron diffraction studies of chain-ordered brownmillerite su...
We are performing structural investigations of a series of brownmillerites (Sr,Ca)2(Fe,Co)2O5 which display long-range modulated ordering of oxygen vacancies at ambient and high... -
Oxygen-deficient quantum spin ice
In quantum analogues of the spin ice materials quantum mechanical tunneling between ground states is expected, and exotic emergent behaviour has been predicted including a Higgs...