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Structure and cation ordering in A2Sn3Q7-type phases (A=In, Cr; Q= S, Se)
We wish to exploit the contrast afforded by neutrons to study the ordering of In and Sn cations in indium tin chalcogenides. Cation ordering has been inferred from spectroscopic... -
muSR study of field-induced phases in a 1-dimensional Ising system
MV2O6 brannerites have a network structure in which chains of edge-sharing MO6 octahedra result in 1-dimensional magnetic properties. A recent study reported monoclinic CoV2O6... -
In situ study of stainless steel martensitic transformation at cryogenic temp...
The mechanical properties of of austenitic stainless steels are thought to be improved by the phenomenon of deformation-induced martensitic transformation, which acts to... -
Investigation of the impact of mechanical twinning on the thermal expansion b...
We request three days of beam-time on POLARIS to investigate the influence of thermally-induced twinning on the thermal expansion behaviour of polycrystalline calcite.... -
Characterisation of superalloys strengthened by Co3Ti
One method by which the efficiency of gas turbine engines may be improved is by increasing the gas stream temperature on entry to the turbine. Currently this temperature is... -
Phase Behaviour in Pyrazine and Tetramethylpyrazine.
Pyrazine-I is stable < 302 K, phase II exists from 302-310 K, and phase III from 310-324 K. The known phase-I forms an ordered structure. It is thought that structures of... -
A µSR study of two different phases of the non-centrosymmetric superconductor...
The intermetallic compound, Re3W is a non-centrosymmetric system with large atomic number (Z) for both constituents (75 for Re and 74 for W) and hence is a good candidate for... -
Transition metal carbides via novel, ultrafast microwave synthesis; Reaction ...
We are investigating the ultra-rapid synthesis of transition metal carbides using microwave (MW) irradiation. Currently we are establishing an understanding of these reactions... -
High temperature phases of SrNdNiRuO6 - Is this unique?
This proposal seeks to determine the structures of the high temperature phases of SrNdNiRuO6 and to investigate the nature of the transitions between them. Iturbe-Zabalo et al.... -
Investigation of the phases formed during the conversion reaction of the C-ba...
FeF2 is a conversion reaction material that undergoes a reaction with lithium: FeF2+2Li++2e-<->2LiF+Fe, which results in a high theoretical capacity, 571 mA/g.... -
Co-surfactancy of oil-soluble and water-soluble surfactants in emulsion stabi...
The structures of emulsions formed from mixed oil-soluble and water-soluble amphiphiles (respectively derivatives of polyisobutylene, PIBSA, and polyacrylamide, PAM) will be... -
The high temperature phases of multiferroic YMnO3
Hexagonal YMnO3 is a well-studied, but poorly understood, multiferroic material, which adopts the 'geometric' mechanism of ferroelectric distortion, rather than the more normal... -
Evolution of internal strains in Mg-Y-Zn alloys containing Long-period Stacki...
There is a great interest in the last years in the study of Mg-Y-Zn alloys containing LPSO phases. This kind of alloys behaves as a metal matrix composite where the LPSO phase... -
Investigation of the low temperature phases of SrSnO3
The present proposal is to examine the low temperature structural properties of SrSnO3 using the HRPD. This work aims to examine the structural basis for the unusual low... -
Electrostatic interaction effects in orientationally disordered phases
Plastic phases are characterized by a positional ordering of the molecular centers of mass while molecules are rotating in a hindered way. Therefore these phases are... -
Topotactically reduced phases containing square planar Co(II) centres
The topotactic reduction of Sr3Co2O5Cl2 and Sr3Co2O5.80 yields the Co(II) phases Sr3Co2O4Cl2 and Sr3Co2O5 respectively. These phases contain corner linked arrays of... -
Enhanced oxygen hyperstoichiometry in Y doped La9.33+xGe6O26+3x/2
Apatite-type lanthanide silicates/germanates have been attracting considerable interest as a new class of oxide ion conductors. The presence of interstitial oxide ions is... -
Mesostructured titania films from ethanolic solutions
In this proposal we wish to continue our current work on mesostructured inorganic films in largely ethanolic solutions, containing limited amounts of water. Transition metal... -
3D neutron TOF diffraction imaging
We propose to use SXD for mapping the crystallographic phases in an extended 3D benchmark object. The phase distribution will be reconstructed using a geometrical aberration... -
The structures of PZT in its ¿rhombohedral¿ phases and their dependence on th...
In the piezoelectric ceramic material PbZrxTi1-xO3 (PZT) there is controversy about the structure of PZT at the Zr-rich end. This region has always been considered to be of...