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Kinetics of Benzene Hydrogenation Revisited in the Presence of Excess Liquid
Heterogeneous catalysis, where the reagents are either contained in a liquid medium, or are liquids in their own right, plays a significant part of the chemical industry. These... -
Investigation of magnetic defects in exfoliated and ball-milled graphite
The recent interest in carbon-based materials like graphene stimulated a deeper analysis of the magnetism in graphite defects. In a previous µSR experiment we observed an... -
The structure of nanographenes in solution
In this proposal we will study the structure of metal-ammonia solutions containing single graphene sheets by exploiting H/D isotopic labelling in conjunction with NIMROD¿s... -
Identification of hydrogenic species on skeletal Ni catalysts
Alloy catalysts are commonly employed for selective hydrogenation of organic molecules due to their enhanced selectivity than individual components but their structural and... -
Powder diffraction studies under high deuterium pressure
The aims of the experiment are (1) to obtain structural data for the model hydrogen storage intermetallic LaNi5 under a deuterium pressure of 3000 bar at cryogenic temperatures,... -
Isotopic Characterisation of Pore Surface Chemistry in Monolithic MCM-41 Subs...
Porous materials impregnated with metal nanoparticles are extremely useful in catalysis, an industry that had a global turnover in 2010 of over three trillion dollars.... -
Probing the Kinetics and Liquid Structure of Toluene Hydrogenation by Pt/MCM-41
In a proof-of-concept beamtime award (RB1220486) we studied the process of platinum-catalysed benzene hydrogenation in the pores of MCM-41 using standard neutron diffraction... -
Low temperarature structure of Sr2CoO2Cu1.85S2
This proposal aims to exploit the superior flux on the upgraded HRPD coupled with the intrinsic high resolution to examine the differences between a sample of Sr2CoO2Cu1.85S2... -
Probing of hydride phase formation of Pd nanoclusters embedded in the NH2-UiO...
With this proposal, we would like to investigate a material that could be used as a catalyst for hydrogenation reactions. A catalyst acts to increase the rate of a reaction by...