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Further investigation of the methanol to gasoline reaction over ZSM-5 using INS
The reaction of methanol to form hydrocarbons over zeolite catalysts is an important option for conversion of natural gas or coal to liquid fuels. We have shown previously... -
CuH: a (nearly) 200 year old problem
Copper (I) hydride, CuH, is unique amongst the binary metal hydrides in that it can be synthesised, at room temperature, in aqueous solution. In recent years CuH generated in... -
The quest for fully hydrogen-ordered ice XIV
Water ice displays a remarkably complex phase diagram containing pairs of hydrogen-ordered / disordered phases. Ice XII is a hydrogen-disordered phase and ice XIV is its... -
Morphology-activity relationships in catalysis promoted by MoOx nanoparticles
Metal and metal oxide nanostructures can be prepared in much different morphology (nanowires, nanobelts, nanofibres etc.) which are known to exhibit better adjustable properties... -
Investigation of the impact of mechanical twinning on the thermal expansion b...
We request three days of beam-time on POLARIS to investigate the influence of thermally-induced twinning on the thermal expansion behaviour of polycrystalline calcite.... -
Understanding deep-Earth mineralogy: The crystal structure of CaSiO3 perovskite
CaSiO3 perovskite is the third most abundant mineral in the Earth's lower mantle (below 670 km). It also occurs as a major phase at lower pressures and temperatures in... -
The application of QENS to investigate the methanol-to-gasoline reaction over...
This proposal requests 6 days of OSIRIS time to conduct QENS measurements on commercial zeolite catalysts which have been removed from a reactor converting methanol to gasoline... -
Copy of: The Effect of Pressure on the Crystal Structure Titanium Tetrachloride
At ambient pressure and temperature TiCl4 is a fuming yellow liquid. On cooling it forma a solid composed of essentially isolated tetrahedral molecules; the same structure is... -
The formation of hybrid organo-metallic perovskites by inverse temperature cr...
Hybrid lead perovskites have received much attention over the past decade since they have potential applications in optoelectronic devices and solar cells. Although most devices... -
Magnetism in novel organic/inorganic hybrid spin-valve nanostructures.
We request 5 days (15 shifts) with CRISP to perform specular measurements on novel functionalized SrTiO3(substrate)/complex FM oxide/small molecules/ FM metal nanostructures to... -
Dynamics of Perfluoroalkanes and Polytetrafluoroethylene
In this experiment we will use the F-mu+-F state as a window into the dynamics of perfluoroalkanes and polytetrafluoroethylene (PTFE) at the molecular level. We will investigate... -
Kinetics of the ordering transition in ice Ih; crystal structure and thermal ...
Below 80 K ordinary water ice (ice Ih) undergoes a phase transition in which the randomly oriented molecules in the crystal adopt an ordered orientation. This ordered form of... -
The application of INS to characterise iron based Fischer- Tröpsch catalysts ...
In conjunction with an industrial partner (Sasol Technology), it is proposed to apply INS to characterize a series of prototype Fischer-Tröpsch synthesis (FTS) catalysts that... -
Neutron Scattering, Agricultural Wastes, Concrete & Water mobility: What can ...
In recent years, the research related to agricultural wastes aiming to evaluate their potential for recycling as well as the elimination of the landfills increased dramatically.... -
Spatial, Chemical, and Temporal Resolution of Platinum-Catalysed Benzene Conv...
This proposal aims to study the potential for neutron diffraction to offer spatially-, chemically-, and temporally-resolved information on a dynamic system, in this case the... -
SANS study of self assembled structures formed from salicylate surfactant in ...
We wish to determine a structure we have observed in a dodecane/surfactant/water system. Initial experimentation has suggested the possibility of spontaneous formation of a... -
Copy of: Pressure induced phase switching magnetic ordering in BiFeO3-PbTiO3
This experiment seeks to continue previous work on PEARL, whereby the phase is altered in the room temperature multiferroic BiFeO3 - PbTiO3 using hydrostatic pressure with the... -
Atomic and pore structure of hetero-atom substituted alluminophosphate materials
We will investigate a series of aluminophosphate systems, in particular related to small pore materials and determine the short and medium range order structures and more... -
3D neutron TOF diffraction imaging
We propose to use SXD for mapping the crystallographic phases in an extended 3D benchmark object. The phase distribution will be reconstructed using a geometrical aberration... -
The Effect of Pressure on the Crystal Structure of Serine Hydrate
Serine monohydrate undergoes a phase transition at 5.2 GPa which involves reorientation of water molecules. It appears that this disrupts H-bonding elsewhere in the crystal,...
