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Effect of the MOF pore structure upon coordinatively unsaturated Cu centres.
Metal-organic frameworks are an exciting class of porous and crystalline materials exhibiting exceptional sorption properties. The growing interest in the community lies in the... -
Topotactically reduced phases containing square planar Co(II) centres
The topotactic reduction of Sr3Co2O5Cl2 and Sr3Co2O5.80 yields the Co(II) phases Sr3Co2O4Cl2 and Sr3Co2O5 respectively. These phases contain corner linked arrays of...