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New brownmillerite-based oxide ion conductors: Local structure and structure-...
Oxide ion conductors are key components in a number of technologically important applications. Our research programme on the development of new oxide ion conductors, using... -
Structural Studies of PbZr1-xTixO3: completing the puzzle in the tetragonal a...
We request 6 days of HRPD time in order to study the structures on the tetragonal side of the lead zirconate-titanate (PZT) phase diagram, a region that has so far been rather... -
Programme Access Rosseinsky
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Magnetic order in a three-dimensional honeycomb iridate
Oxides of 5d elements such as Ir and Os have been attracting much attention as candidates to realize novel types of electronic ground states stabilized by the strong spin orbit... -
Apatite-type Oxides for Energy Applications: Role of Lattice Dynamics
Lanthanum-containing germanate apatites are materials with potential applications as electrolytes in solid oxide fuel cells. The conductivity of these materials is known to... -
Electronically-driven structural transition in Ti-doped Ca3Ru2O7
The purpose of the experiment is to determine the effect of titanium doping on the structural and magnetic transitions of Ca3Ru2O7. The pure material undergoes a Néel transition... -
In-situ studies of amides with ammonia
The aim of this proposal is to determine that materials that are present in the ammoniation of amides. -
Hydrogen production from ammonia using lithium imide: an isotope study
We have recently discovered that light metal amides and imides are excellent cattalysts for the decomposition of ammonia. We request 3 days on POLARIS to perform in situ neutron... -
Understanding the decomposition of ammonia by lithium-calcium imide
Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data... -
Towards the development of carbonitrides as novel two-stage regenerable reage...
We are examining a number of cobalt-molybdenum carbonitrides as possible catalysts for reactions that produce nitrogen-containing organic molecules. There is good evidence that... -
In-situ neutron powder diffraction study of the synthesis of Half-Heusler the...
XNiSn (X = Ti, Zr, Hf) Half-Heusler materials are potential candidates for application in thermoelectric waste heat recovery. The aim of the experiment is to follow the... -
The Definitive Sodium Niobate Phase Diagram?
NaNbO3 has long been regarded as the 'most complex' perovskite known, with at least seven different phases reported as a function of T, at least two of which have evaded all...