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Probing diffusion of renewable feedstocks in single-site nanoporous materials
Silicon-doped aluminophosphates (SAPOs) are framework materials similar to zeolites. Their pore structure and solid acid sites contribute to their activity and selectivity in... -
Clarifying the interaction between cyclic oxime and acidic silanols in hierar...
Caprolactam (CL) is a high-value chemical and precursor to nylon-6. Industrially, a harsh, liquid acid catalyst transforms C6-oxime to CL but due to the risk and inefficiency of... -
Role of acidic silanols and Brønsted acid sites in hierarchically porous SAPO...
The commercially important polymer Nylon 6 is manufactured by ring-opening polymerization of eta-caprolactam. Industrially, eta-caprolactam is conventionally made by the... -
Role of acidic silanols and Brønsted acid sites in hierarchically porous SAPO...
The commercially important polymer Nylon 6 is manufactured by ring-opening polymerization of eta-caprolactam. Industrially, eta-caprolactam is conventionally made by the... -
Atomic and pore structure of hetero-atom substituted alluminophosphate materials
We will investigate a series of aluminophosphate systems, in particular related to small pore materials and determine the short and medium range order structures and more...