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The structure of methanol in halloysite nanotubes
Understanding the structure of liquids in nanopores and at interfaces is extremely important in many natural and industrial processes. In this experiment, we will use the unique... -
A total scattering study of the concentration and temperature dependence of s...
Lithium-ion batteries (LIBs) are ubiquitous in our portable electronics, however they are ill suited for applications where cost or sustainability are of paramount importance,... -
The structure of polar aprotic solvents in cylindrical nanopores
The aim of this experiment is to understand the structure of two widely used polar organic solvents, N,N-Dimethylformamide (DMF) and N-Methyl-2-pyrrolidone (NMP), in cylindrical... -
Temperature-Dependent Structural Changes in Liquid Benzene
The non-covalent interactions between aromatic rings are of fundamental importance in large number biological and chemical processes. The local structure of aromatic liquids is... -
Understanding the molecular origin of co-non-solvency. Step 2.
A number of polymers that are commonly soluble in water and in alcohol, display a dramatic collapse when 10 molar % of alcohol is added to the polymer/water system. Various... -
Hydrocarbon Fluid Structures in Nanoconfinement
Shale or tight oil is trapped in nano-porous rocks and is expected to play a key role in the energy supply in the future. Due to confinement, trapped fluids exhibit changes in... -
Solvation structures of cyclic compounds: the crown ethers
Crown ethers are cyclic molecules formed by joining ether groups into a ring. These compounds have many interesting solution properties, including their ability to bind strongly... -
Understanding Sulphur and Nitrogen-Aromatic interactions from liquid structure
Asphaltenes are a complex and problematic fraction of crude oil that can precipitate, alter wettability and stabilise unwanted oil-in-water emulsions. Asphaltenes have a high... -
When like-charged ions attract: Size and distribution of cationic clusters in...
Contrary to the strong electrostatic repulsion between like charged ions, last year the Ludwig group, used IR and NMR spectroscopy combined with computational methods, to reveal... -
Metal Ion Solubility in Deep Eutectic Solvents
Recent work on deep eutectic solvents (DES) has demonstrated that these novel H-bonded liquids can be used to modify nanomaterial morphologies under mild conditions in... -
Resolving the enigma of self-assembled meso-structures in an H-bonding rich m...
In a recent successful LOQ experiment (RB 1810629), we have unexpectedly observed possible multilayer stacking of sodium dodecyl sulfate (SDS; ~2wt%) bilayers in glycerol... -
Specific ion effects in molecular non-aqueous electrolytes
Specific-ion (Hofmeister effects) are ubiquitous whenever ions are dissolved in solution and are important in many research fields from chemistry, to biology and in materials... -
When like-charged ions attract: How OH-defects influence the size and distrib...
This study will probe the liquid nanostructures of mixtures of two ionic liquids, 4-(hydroxybutyl)-pyridinium-bis(trifluorosulfonyl)-imide ([HOC4Py]NTf2) and... -
Solvation structure of sodium ions and hexa-fluorophosphate ions in organic c...
Here we propose to study the local structure of sodium in standard organic carbonate electrolytes for sodium ion batteries. Three different electrolytes are chosen to study; a... -
Structure and solvation of LiNTf2/1,2,3-trimethoxypropane - a new bio-derived...
This work will study the structure a new lithium-based electrolyte produced using 1,2,3-trimethoxypropane, a bioderived low-toxicity green solvent, as a first stage towards the... -
The origin of the dissolution of cellulose in NaOH/urea aqueous solution at -...
Cellulose is produced over tens of billions of tons every year in the world. It is the one of the most abundant natural polymer resources. Compared with petroleum-based... -
When like-charged ions attract: How OH-defects influence the size and distrib...
This study will probe the liquid nanostructures of mixtures of two ionic liquids, 4-(hydroxybutyl)pyridinium-bis(trifluorosulfonyl)-imide ([HOC4Py]NTf2) and... -
Solvent-solute interations in PET recycling systems
Glycolysis of polyethylterephthalate (PET) catalysed by ionic liquid solvents could offer a metal-free low cost approach to chemical recycling of waste PET. This work will... -
Linking the solid state and solution thorium aqua structures: solution struct...
A understanding of the aqueous chemistry of the actinide ions is not as well developed as for transition metals or the lanthanides. Fundamentally important information such as... -
Water structure in C-A-S-H by neutron diffraction with isotopic substitution:...
The manufacture of every ton of cement emits approximately 0.8 tons of CO2 into the atmosphere, comprising 57% of the global human-made CO2 emissions. A low pH - low CO2 class...