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Structural studies of the cycling and decomposition of Mg(NH3)6(BH4)2
Given its high hydrogen gravimetric density, ammonia may be utilised as a hydrogen carrier, and thus ammonia stores are an area of interest. It is known that Mg(BH4)2 takes up... -
Investigation of molecular rotation and disorder in methylamine borane (CH3NH...
We request 3 days on TOSCA to study molecular rotations of NH4+ and BH4- ions and the ionic disorder in ammonium borohydride (rock salt lattice) and its methylated derivative.... -
In-situ Gravimetric Study of the Decomposition of Alkali Metal Amidoboranes
We request 3 days on HRPD with the IGAn apparatus, to perform in-situ neutron diffraction and thermogravimetric studies of the decomposition of deuterated alkaline amidoboranes.... -
Me-ND311BD4: a temperature dependent study of its crystal structure and decom...
We request 4 days on HRPD with the IGAn apparatus to follow the structural changes of Me-ND4 11BD4 as a function of temperature. The high resolution of HRPD will allow us to... -
Study of NH4+ mobility in ammonia borane, ammonium borohydride and methyl amm...
We request 5 days on EMU to study the NH4+ ion mobility in the light borohydride materials NH3BH3, NH4BH4 and CH3NH3BH4. As has been proposed by Stowe et al., during the...
