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Modes of pi-stacking in neat and aqueous solutions of 1-naphthyl-3-methylimid...
The proposed work continues our investigations of the structure, aggregation, self-assembly and ion pairing of ionic liquids in the neat state, at interfaces, and in solutions.... -
Insight into the adsorbed water layer of hydration shells around iron oxide n...
With this proposal we want to study the (deuterated) hydration shell of facetted iron oxide nanoparticles (IONPs). IONPwater interfaces are of great importance for biomedical... -
Model Amphiphilic Deep Eutectic Liquids
Deep eutectic liquids (DELs) - mixtures of high melting-point solids that form stable liquids near room temperature ¿ have recently emerged as a new class of novel solvents with... -
Local and long-range ordering in concentrated nanotube solutions
Manipulating nanoparticles in liquids is crucial for their scalable implementation in future technologies. For example, such liquids can be used like paint to create uniform... -
Local and long-range ordering in concentrated nanotube solutions
Manipulating nanoparticles in liquids is crucial for their scalable implementation in future technologies. For example, such liquids can be used like paint to create uniform... -
Role of DMSO in Ionic Liquid / DMSO Mixtures
This proposal aims to study the interactions within a prototypical ionic liquid / co-solvent system. Such systems are currently under investigation as potential solvating media... -
Probing the Kinetics and Liquid Structure of Toluene Hydrogenation by Pt/MCM-41
In a proof-of-concept beamtime award (RB1220486) we studied the process of platinum-catalysed benzene hydrogenation in the pores of MCM-41 using standard neutron diffraction... -
Spatial, Chemical, and Temporal Resolution of Platinum-Catalysed Benzene Conv...
This proposal aims to study the potential for neutron diffraction to offer spatially-, chemically-, and temporally-resolved information on a dynamic system, in this case the... -
Structural organization of an acqeous biphasic system for the use of metal re...
Aqueous biphasic systems have been recently proposed for metal separation, using an acidic-ionic liquid based solution. Metals are dissolved in ternary mixture and migrate... -
Structural behavior of subcritical and supercritical carbon dioxide confined ...
Shale is an increasingly important source of natural gas and potential candidate for carbon dioxide sequestration. Understanding the gas adsorption behavior on shales is of key... -
Local and long-range solute and solvent ordering in concentrated nanotube gel...
Manipulating nanoparticles in liquids is crucial for their scalable implementation in future technologies. For example, such liquids can be used like paint to create uniform... -
Determining the Vibrational Frequencies and Lattice Dynamics in Nanoporous Ze...
This proposal will use Inelastic Neutron Scattering (INS) spectroscopy at TOSCA to establish the vibrational frequencies in nanoporous zeolitic imidazolate framework (ZIF)... -
Cononsolvency of Poly(N,N-Diethyl Acrylamide) (PDEA) in water/ethanol mixture...
Cononsolvency is a rare phenomenon that the solubility of a polymer decreases or even vanishes in the mixture of good solvents [Macromolecules 1991, 24, 948]. Although PDEA is... -
Spontaneous solvation of graphene from KC24(NH3) and KC8 graphite intercalati...
Liquid phase exfoliation of graphite is a scalable method for the production of graphene with an inbuilt medium for the manipulation of the graphene into applications. Much like... -
Evolution of interlayer water to form gel-like layers in graphene oxide
Graphene oxide is a heavily functionalised form of grapheme that is dispersible in water and other solvents. As water is added to pristine graphene oxide there is formation... -
Solution structures of aqua complexes of uranium in different oxidation states
The safe storage of spent nuclear fuels in an underground repository requires the fundamental chemistry to be well understood so predictions of solubility behaviour over 100,000... -
Investigation of the Interactions Between Porous Frameworks and Adsorbed Gas ...
We request a total of 9 days on TOSCA:6 days to investigate the interactions exhibited by two Li containing metal-organic framework materials on loading with CO2. Doping of Li... -
Understanding Amphiphilic Self-Assembly in and by Protic Ionic Liquids
The goal of this project is to understand the intermolecular forces that promote amphiphile self assembly in ethylammonium nitrate (EAN), a room temperature ionic liquid (IL).... -
Study of nano-electrode materials for Li-ion batteries combining small-angle ...
Nano-materials are of interest in the field of energy conversion and storage due to properties not seen for the bulk. However, due to their non-periodic nature, the atomic... -
Protein-Ionic liquid interactions: A window into future sustainable processin...
Processing of complex biopolymers, particularly proteins such as keratin and silk, has been hindered by the extremely low solubility and thus accessibility to the protein...