28 datasets found

Reticular chemistry provides materials designers with a practically infinite playground on different length scales. However, the space of all plausible materials for a given...

Knowledge of the oxidation state of a metal centre in a material is essential to understand its properties. Chemists have developed theories to predict the oxidation state based...

Knowledge of the oxidation state of a metal centre in a material is essential to understand its properties. Chemists have developed several theories to predict the oxidation...

Pyrene is one of the most widely investigated aromatic hydrocarbons due to its unique optical and electronic properties. Hence, pyrene-based ligands have been investigated for...

Pyrene is one of the most widely investigated aromatic hydrocarbons due to its unique optical and electronic properties. Hence, pyrene-based ligands have been investigated for...

We report the synthesis of Al-TFS, a novel aluminum metal-organic framework (MOF) based on tetrafluorosuccinic acid (H₂TFS), of formula Al(OH)(TFS)·1.5H₂O, introducing a new...

Metal-Organic Frameworks (MOFs) are highly versatile materials owing to their vast structural and chemical tunability. These hybrid inorganic-organic crystalline materials offer...

Finding heterogeneous catalysts that are superior to homogeneous ones for selective organic transformation is a major challenge in catalysis. Here we show how micropores in...

The vast chemical space of metal and ligand combinations in Transition Metal Complexes (TMCs) gives rise to a rich variety of electronic excited states with local and non-local...

Metal-organic frameworks (MOFs) consist of metal nodes that are connected by organic linkers. They are thus highly chemically tunable materials given the broad range of...

The heat capacity of a material is a fundamental property that is of significant practical importance. For example, in a carbon capture process, the heat required to regenerate...

An interesting In(III)-framework has been synthesized at the University of Nottingham by the group of research of Martin Schroder. This metal-organic framework is based on...

Metal-organic framework (MOF) materials are a kind of inorganic-organic hybrid materials with a open modular molecular architecture. Such a modularity opens a plethora of...

The energy costs associated with large-scale industrial separation of light hydrocarbons by cryogenic distillation could potentially be lowered through development of selective...

The development of new functional metal-organic frameworks (MOFs) as complex proton conductor is receiving increasing attention worldwide. We aim to develop new solid proton...

At ambient pressure TiCl4 forms a molecular solid consisting of isolated TiCl4 molecules (phase-I). At 0.5 GPa this structure undergoes a transition to phase-II, which is...

In the current proposal, we require TOSCA to investigate by vibrational spectroscopy the apparent amorphous nature of the prototype drug molecule ibuprofen confined by...

High surface area, functionalized metal-organic frameworks (MOF) have been shown to not only capture CO2, but to selectively do so over other gases like nitrogen. There are both...

Zeolitic imidazolate frameworks (ZIFs), a sub-family of MOFs, have recently been observed to melt, with the liquid surprisingly retaining the chemical composition of the...

Three MOFs samples with high hydrogen storage capacities at 77K, and high surface area, are willing to be analyzed. In order to investigate hydrogen interactions within the...