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Investigation of glycolide-h4 and d4 at high pressure.
This proposal seeks to investigate the polymorphism and polymerisation of glycolide. Glycolide is a six-memebered ring structure that polymerises into poly(glycolic acid) and is... -
Neutron Training Course
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LOW DIMENSIONAL NETWORKS UNDER PRESSURE. IN-SITU DIFFRACTION MEASUREMENTS OF ...
Carbonate liquids are characterised by low temperature and low viscosity and play an important role in molten carbonate fuel cells, battery electrolytes and, surprisingly, in... -
The effect of pressure on the hydrogen bonding in ammonium formate
We propose to investigate the changes that occur in the structure of ammonium formate as a function of pressure. This is the simplest system in which the oxygen atoms of a... -
Thermoelastic properties of ammonium sulfate, (ND4)2SO4, and the P-T dependen...
Ammonium sulfate exhibits a first-order phase transition upon cooling through ~ 224 K at room pressure, from a paraelectric to a ferroelectric crystal. There have been no... -
Insulator to metal transition in TiOCl at high pressures
We propose to study the high temperature structure of TiOCl where a pressure induced metal to insulator transition has been reported recently by Kuntscher et al.Due to our... -
Copy of: The Effect of Pressure on the Crystal Structure Titanium Tetrachloride
At ambient pressure and temperature TiCl4 is a fuming yellow liquid. On cooling it forma a solid composed of essentially isolated tetrahedral molecules; the same structure is... -
High-pressure structure of ferrosilite FeSiO3 glass
The density-driven structural transformations in ferrosilite glass FeSiO3 will be investigated at pressures increasing to 17.5 GPa. This glass is one of a family of silicate... -
A High pressure investigation of the Binary carbonyls of group 7 M2(CO)10 M =...
The structures of two binary metal carbonyls containing a metal-metal bond Mn2(CO)10 and Re2(CO)10 will be studied as a function of pressure. Both these molecules undergo a... -
Determination of the Thermoelastic Properties of Jadeite
Jadeite, NaAlSi2O6 is an important mineral in metamorphic rocks and occurs in low as well as high metamorphic grade. Previously we have determined the thermoelastic properties... -
Phase Behaviour in Pyrazine and Tetramethylpyrazine.
Pyrazine-I is stable < 302 K, phase II exists from 302-310 K, and phase III from 310-324 K. The known phase-I forms an ordered structure. It is thought that structures of... -
Neutron Total Scattering of Crystalline Materials in the Gigapascal Regime
Over the past few years, extensive developments have been made in the use of neutron diffraction for structural studies of liquids and amorphous materials at high pressure.... -
Pressure-induced proton migration in an energetic co-crystal
The results of these studies will provide valuable information on the effects of extreme conditions on the structures of an energetic salt and co-crystal formed between... -
Towards Neutron Scattering of Amorphous Materials in the Gigapascal Regime
Over the past few years, extensive developments have been made in the use of neutron diffraction for structural studies of liquids and amorphous materials at high pressure.... -
Comparison of the Compression Behaviour of BaSnO3 and Ba0.575Sr0.425SnO3
We propose to study the effect of pressure on the structure of the tetragonal Ba0.575Sr0.425SnO3, The behaviour will be compared to the compression of the cubic BaSnO3 (parent... -
Polymorphism and polymerisation of methacrylic acid
This proposal seeks to explore the polymorphism and polymerisation of methacrylic acid using high pressure. We have recently studied acrylic acid at high pressure using single... -
High pressure structural study of BaD2
Simple hydrides are of scientific interest due to their suitability for storage of hydrogen in the solid state. These materials also display a wealth of interesting physics,... -
Investigation of glycolide-h4 and d4 at high pressure.
This proposal seeks to investigate the polymorphism and polymerisation of glycolide. Glycolide is a six-memebered ring structure that polymerises into poly(glycolic acid) and is... -
High-Pressure Investigation of the Ferroelectric ND4IO3
We propose a high-pressure neutron powder diffraction study of the crystal structure of deuterated ammonium iodate, ND4IO3, which is known to undergo a ferroelectric phase... -
Understanding the Pressure Response in Amines: Weak hydrogen-bonding vs Non-b...
Methylamines are an ideal chemical system to study in order to understand the effects of steric bulk and competing non-bonding interactions on hydrogen bonding at the networks...
