-
Structural phase transitions in Li doped AgNbO3.
The aims of the present proposal are twofold. Firstly to use very high resolution neutron diffraction data to establish accurate and precise structures of the novel... -
Understanding the decomposition of ammonia by lithium-calcium imide
Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data... -
Probing structural subtleties in hydrated lithium-rich anti-perovskites (LiRAPs)
Many of the devices currently used for energy storage (e.g., batteries, solar cells) use liquid electrolytes that are known to pose a serious fire and safety risk. However, the... -
Hydrogen production from ammonia using lithium imide: an isotope study
We have recently discovered that light metal amides and imides are excellent cattalysts for the decomposition of ammonia. We request 3 days on POLARIS to perform in situ neutron... -
Spatial, Chemical, and Temporal Resolution of Platinum-Catalysed Benzene Conv...
This proposal aims to study the potential for neutron diffraction to offer spatially-, chemically-, and temporally-resolved information on a dynamic system, in this case the... -
The possibility of strongly ferromagnetic austenite in a stainless steel
It is generally accepted that austenitic steels (fcc) show no ferromagnetic signature. However, thermomagnetic measurements suggest an unexpected ferromagnetic transition (Tc =... -
Sensing Sulphur Dioxide in Robust Porous MOF Materials via Simultaneous Micro...
We seek to develop new materials for sensing and removal of toxic gases (esp., SO2) and request 2 days on POLARIS to study the structural binding details and dielectric data... -
Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and... -
What is the Room Temperature Structure of NaTaO3?
The current proposal seeks to establish the origin of t non-perovskite-like peak splitting observed in HRPD data for NaTaO3. It is our hypothesis that this is a result of the... -
What is the Room Temperature Structure of NaTaO3?
The current proposal seeks to establish the origin of t non-perovskite-like peak splitting observed in HRPD data for NaTaO3. It is our hypothesis that this is a result of the... -
Understanding the formation of diamonds: Calibrating the coesite solid-inclus...
Diamonds provide our only direct samples of the very deep Earth and understanding their origin is consequently of great interest to Earth Scientists. The origin of diamonds can... -
In-situ neutron powder diffraction studies of non-stoichiometry in Na battery...
We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium... -
In-situ diffraction studies of ammonia decomposition over iron, ruthenium and...
We request 3 days beam time on POLARIS for the in-situ study of the crystalline phase composition of iron, manganese and ruthenium catalysts for ammonia decomposition. These... -
Structural studies of thermochemical and phase-change naterials for heat storage
This proposal seeks to study three systems associated with heat-storage applications using in situ neutron powder diffraction. The first experiment will focus on a sample of... -
Crystal structure and phase transitions of Sr2IrO4
Sr2IrO4 is an important material in the field of condensed matter physics, being a proposed J_eff=1/2 Mott insulator. Recent publications have shown that the reported low- and... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
Simultaneous Microwave Dielectric Spectroscopy and Neutron Diffraction Measur...
Ammonia has been proposed as a high density chemical energy-storage media, which can be safely and reversible stored within low cost saline halides. Here we propose to extend... -
In-situ studies of alkaline earth nitride deuterides
Heavy alkaline earth nitride hydrides (AE2NH, with AE = Ca and Ba) are of interest due to their potential suitability as electrolyte materials in a variety of electrochemical... -
Sensing SO2 in Robust Porous MOF Materials via Simultaneous Microwave Dielect...
We seek to develop new MOFs for sensing and removal of toxic gases (e.g., SO2) and request 4 days on POLARIS to study the structural binding details and dielectric data... -
Simltaneous dielectric spectroscopy and neutron diffraction
We have constructed a novel microwave frequency resonator that can sit within the GEM and POLARIS diffractometers and will allow us to simultaneously collect diffraction and...