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Recovery and characterisation of high-pressure phases in the systems H2O ¿ NH...
The objective of this experiment is to characterise four particular high-pressure polymorphs of various hydrates discovered by us in recent years during work carried out using... -
A high pressure study of the novel hybrid improper ferroelectric HgMn7O12
We have recently discovered how a novel type of hybrid improper ferroelectricity can arise in the perovskite HgMn3Mn412. This ferroelectricity is driven by a highly unusual... -
The Pressure and Temperature Dependence of the Structure of Ammonium Triiodide
We have shown that the molecular ionic solids MI3 (M=Tl, Cs, Tl, NH4) undergo structural phase transitions below 3.4 GPa at RT to give the same new high pressure phase (HP) with... -
Network compression and pressure-induced amorphisation in Zn(CN)2
Zn(CN)2 is an important material because it shows isotropic NTE over a large temperature range and to an extent more than double that of ZrW2O8. This unusual behaviour... -
PT-phase diagram of ammonium bromide
Ammonium bromide is a fundamental ionic solid that finds practical use, industrially, as a highly-effective flame retardant and also as an intermediary source of bromide in...