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Controlling the morphology of bulk heterojunction (BHJ) films using mixtures ...
We have recently demonstrated that in organic photovoltaic devices (OPVs) the additive 1,8-diiodooctane (DIO) largely remains in the film after spin-coating acting as a... -
The pressure dependence of the decomposition temperature of methane hydrate i...
The properties of methane ammonia water mixtures are crucial for models of how the outer planets evolved and yet have not been much studied. This proposal is for beamtime to... -
Dirac Point and Topological Triplon Bands in the Shastry-Sutherland Material ...
SrCu$_2$(BO$_3$)$_2$ (SCBO) is a very much studied quantum magnet that is most well known for its ground state of coupled singlets and multiple magnetization plateaux. Recently,... -
In-situ neutron powder diffraction studies of non-stoichiometry in Na battery...
We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium... -
Organisation of Outer membrane protein F at the air/liquid interface
Crystallisation of membrane proteins as a precursor to high resolution structural studies is a significant research bottleneck. We are investigating alternative methods to... -
Probing the structure of polymer stabilised foams
Polyurethane foams (PUFs) are commonly prepared by mixing Pluronic type copolymers and isocyanate reactive monomers in the presence of additives e.g. catalysts, blowing agent... -
In-situ Neutron Diffraction Studies of Lithium Battery Materials
This proposal seeks to test a new battery designed to allow in situ neutron diffraction measurements of lithium ion battery electrodes under charge and discharge. We have... -
In-situ diffraction studies of ammonia decomposition over iron, ruthenium and...
We request 3 days beam time on POLARIS for the in-situ study of the crystalline phase composition of iron, manganese and ruthenium catalysts for ammonia decomposition. These... -
Combined in-situ structural and hydrogen desorption/absorption studies of hyd...
The Li?N?H hydrogen storage system is one of the most promising candidates for hydrogen storage in vehicular applications and the addition of halide ions significantly increases... -
In-situ diffraction and TGA of the hydration reaction of proton conducting pe...
Here the use of the IGAN system for in-situ TGA and neutron diffraction is proposed in order to study the de-hydration of four proton conducting materials. The selected... -
Quantum critical dynamics in the purely dipolar antiferromagnet LiErF4
LiErF4 is an example of an XY dipolar coupled antiferromagnet with planar anisotropy. As such it exhibits a quantum phase transition (QPT) in a small field of 4kOe, which is of... -
Reflectometry studies of the mechanism of formation of mesoporous silicate fi...
Surfactant-silica self-assembly processes have been extensively studied since the discovery of M41S mesoporous materials in 1992. Mesoporous silicate films can be grown from... -
Single-Crystal Neutron Diffraction Study on [U(C5Me5)2(H)(mu¿H)]2
To our knowledge, the length of the U¿H single bond has never been accurately measured, at least not in a molecular compound by single-crystal neutron diffraction. We currently... -
In Search of Superionic Conductivity of Mg2+ Cations
The migration of cations with a charge greater than 1 has received very little attention historically, perhaps due to no commercially driven demand for the research as well as... -
Effect of pressure-transmitting medium on the phase transformation of para-am...
The pressure-transmitting medium in a high-pressure experiment is usually thought of as an inert medium that allows the sample to be compresses rather than crushed. In organic... -
Structural studies of thermochemical and phase-change naterials for heat storage
This proposal seeks to study three systems associated with heat-storage applications using in situ neutron powder diffraction. The first experiment will focus on a sample of... -
Pressure dependence of the crystal structure of the strongly correlated bilay...
Ruthenium-oxides are important strongly correlated electron systems: the bilayer ruthenate Sr3Ru2O7 shows field-induced electronic order, while single-layer Sr2RuO4 is an exotic... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
Building a comprehensive understanding of cation ordering in the commercial c...
The objective of the proposed experiment is to develop an understanding of the Li/Ni/Mn ordering in a commercially relevant lithium ion battery positive electrode,... -
Simultaneous Microwave Dielectric Spectroscopy and Neutron Diffraction Measur...
Ammonia has been proposed as a high density chemical energy-storage media, which can be safely and reversible stored within low cost saline halides. Here we propose to extend...
