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Reflectometry studies of the mechanism of formation of mesoporous silicate fi...
Surfactant-silica self-assembly processes have been extensively studied since the discovery of M41S mesoporous materials in 1992. Mesoporous silicate films can be grown from... -
manipulating surface adsorption usinf ethoxylated polyelectrolytes
The strong interaction between polyelectrolytes and ionic surfactants can result in pronounced surface adsorption and the formation of surface multilayer structures. This... -
Sub-micron structure of conjugated polymer interfaces
There are two contributions to the rms roughness of a polymer-polymer interface; i) the so-called ¿intrinsic interfacial width¿ due to mixing of the polymers at a molecular... -
Probing the wetting transition in a semiconducting liquid crystal thin film b...
The aim of this experiment is to study the nucleation and molecular layer-by-layer growth of a 'thin film' (TF) phase at the buried substrate interface of thin films of fully... -
Surface adsorption of short peptide surfactants
Short peptide sequences consisting of hydrophobic and hydrophilic amino acid units are capable of self-assembly to lead to interfacial adsorption and solution nano-aggregation.... -
The hydration and ordering of lamellar block copolymer films prior to the for...
For polymer vesicles to act as effective molecular delivery systems we must efficiently encapsulate a molecular payload within the vesicle. We would like to use neutron... -
Multi-component mixtures of biosurfactants and conventional surfactants
This proposal is about the development of sustainable detergency based formulations, based on the blending of biosurfactants and conventional surfactants, and is part of a CASE... -
Effects of Architecture on Polymer Diffusion
As part of a wider study we are investigating the effects of polymer architecture between cyclic and linear polymers. From ATR-FTIR measurements we observe clear differences... -
Competitive adsorption of Fatty acid, Phosphoric acid and Sulphonic acid salt...
This proposal presents a comparative study of the adsorption of three key chemical groups onto an important technological substrate, viz. fatty acid salt (Sodium hexanoate),... -
Interaction between the bioactive lipopeptide fengycin and lipid membranes
One class of bioactive lipopeptides produced by Bacillus subtilis, fengycin, has strong surfaceactivity and interesting antifungal property with low hemolytic activityTo gain... -
Diffusion Kinetics in Multilayer Organic Films for OLEDs
Conjugated organic semiconductors form an exciting class of materials that can be used in a variety of cutting edge technologies including organic light-emitting diodes (OLED),... -
Time Resolved Studies on Inorganic Film Formation at the Air-Solution Interface
In a recent SURF experiment on the formation of silica films templated with cat-anionic/polymer complexes we found that the film growth and evolution occurs on a faster time... -
Partial structural study at the oil-water interface
In our previous experiment we determined a value for the interfacial width of bare hexadecane-water interface. The NR-determined width was 6.0 ± 1.0 Å, which compares well with... -
Competitive adsorption in hydrophobin-surfactant mixtures
Hydrophobins are small compact secreted fungal proteins which are strongly surface active and adhere to both hydrophobic and hydrophilic surfaces. Their strong surface activity... -
Characterisation of bioadhesive protein-PEG conjugates grafted to titanium su...
Summary: Titanium implants are surgically important and require a hydrophilic polymer coating to prevent biofouling in situ. Bioadhesive proteins can be covalently tethered to... -
Kinetics and growth mode of aggregation phenomena inside polymer brushes
We will use time-resolved specular neutron reflectivity measurements to follow the in-situ growth of polymer brushes by surface-initiated ATRP. This will enable us to determine... -
Anomalous Layer at a Nematic-Air Interface using Thin Films
The aim is to establish the nature of the surface layer of 8CB at the nematic-air interface by measuring neutron reflection from the n=8, 10 and 12 homologues of the nCB series... -
A study of protein adsorption via chelating lipids within a solid supported l...
The crystallisation of membrane proteins is of great interest, not least, to the pharmaceutical industry. We have recently begun a project aiming to investigate the role played... -
Spontaneous multilayer formation at interfaces in mixed surfactant systems
The spontaneous formation of multilayer structures at interfaces from surfactant self-assembly has until recently been rarely observed. However, surface multilayer structures... -
How perfume structure affects surface coadsorption with anionic surfactants
In a recent EPSRC / Unilever / Oxford CASE project we have used NR to explore and develop optimised delivery mechanism for active benefit agents such as perfumes. In particular...
