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Magnetic order in weakly coupled molecular magnetic systems
Two molecular magnetic systems are considered which show low-temperature ordered states. One of them is F4BImNN, a nitronyl nitroxide radical magnet, an excellent realization of... -
Isolating exchange pathways in novel molecular magnets
Experimentally exploring the fascinating physics of one- and two-dimensional magnetism continues to rely on the synthesis of novel, model systems with highly anisotropic... -
How molecular solids prepare for phase transitions: The phase transition in o...
Oxalyl chloride, which is a liquid at RT, forms a disordered phase (I) on cooling to 260 K. This phase is unstable with respect to an ordered phase (II) below 250 K, but in... -
High-pressure studies of energetic materials
This proposal seeks to identify and characterise high-pressure polymorphs of the energetic materials hydroxylammonium perchlorate, CL-20, diaminodinitroethene (FOX-7), and... -
Effect of pH on the shape of oil-in-water microemulsions formed by a zwitteri...
Despite interest in microemulsions as drug delivery vehicles, there is a lack of structural understanding to justify the formulations used. The present study examines the use of... -
Understanding the structure of constrained polymer thin-films: ¿artificial an...
The Mayes' group at UEA is world-leading in investigating core-shell nanoparticles as a promising format for 'synthetic antibodies', based on molecular imprinting. One of the... -
Magnetic properties of photomagnetic molecular square complexes
This experiment aims at studying the magnetic behaviour of the molecular square complex {[Fe{B(pz)_4}(CN)_3]_2[Co(bik)_2]_2}(ClO_4)_2 . 3H_2O [B(pz)_4 = tetrapyrazolylborate,... -
Investigating the reduction kinetics of high molecular weight metal oxides in...
There is a pressing worldwide need for research to develop specific sustainable spent fuel reprocessing technologies suitable for minimizing waste from next generation nuclear... -
Level crossings in the open ring molecular magnet Cr8Cd
Molecular nanomagnets (MNMs) comprise clusters of exchange coupled transition metal ions which often have a negative anisotropy constant, favoring a ground state with a large... -
Hydrogen Disorder in the molecular complex 5-fluorocytosine: 3,5-dinitrobenzo...
As part of our program in understanding hydrogen bonding systems, exploiting crystal engineering in our synthesis of complexes containing desired HB motifs, we investigate... -
Level crossings in open ring molecular magnets
Molecular nanomagnets (MNMs) comprise clusters of exchange coupled transition metal ions which often have a negative anisotropy constant, favouring a ground state with a large... -
Towards a validated standard method for performing DFT calculations of muoniu...
In this proposal we want to address the issue of the identification of the different muonium adducts that are possible in Alq3 without any crystallographic constraints, and... -
Structure of hot dense liquid carbon dioxide
We propose to study the structure of liquid CO2 by neutron diffraction under high pressure and high temperatures to 6 GPa / 800 K. Carbon dioxide belongs to the most fundamental... -
How molecular solids prepare for phase transitions: The phase transition in o...
Oxalyl chloride (mpt. 260 K), forms an ordered phase at low temperature, but a disordered phase between 250 K and the melting point. In previous beamtime we aimed to carry out... -
Probing membrane localisation of molecular rotors (NR)
A number of important biological processes, such as intracellular transport and signal transduction depend on the viscosity and the distribution of microdomains in cells. We... -
Quasi two-dimensional molecular layers separated by magnetic and non-magnetic...
One goal of our research into the nanoengineering of molecular magnets is a detailed understanding of the relationship between the structure and composition of a system and its... -
Nonmonotonic phase diagrams in molecular magnets
We propose longitudinal field muSR on a 2D molecular magnetic system which has been suggested to have an unusual B-T phase diagram. Our goal is to probe the transition from... -
Revising the onset of anharmonicity in proteins
Our previous INS studies of ¿dry¿/hydrated apoferritin show that the hydrated protein undergoes a dynamical transition, Td, at 200K. Such behavior, first modeled by Doster et al... -
Dynamics within the Plastic Crystal Phases of Hydrogen Chloride
Hydrogen chloride exhibits a complex phase diagram account made of its simple molecular structure. Three crystalline phases are known to exist at ambient pressure below its... -
Spin relaxation of short-lived spin-labelled radicals in solution
The spin relaxation rates of free radicals in solution can provide valuable information about the dynamics of molecular tumbling in solution, and solvent-radical interactions....
