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The high pressure structures of ammonium fluoride
Ammonium fluoride is an ionic H-bonded analogue of ice. Its behaviour is thus of interest as a comparator for ice. This proposal is for beamtime to make the first neutron study... -
The crystal structure and thermal expansion of orthorhombic NiSi
NiSi is a technologically important material that is also of interest to Earth Scientists because of the possible role of Ni and Si in the Earth¿s core. It crystallises in the... -
Does the viscosity of the sub-phase effect the oxidation kinetics of surface ...
Atmospheric climate change is strongly influenced by clouds and the oxidative processing of pollutants in clouds affects droplet size and reflectivity of the planet. Clouds... -
Crystal structures of methanol mono-ammoniate (CD3OD.ND3) and methanol hemi-a...
Mixtures of methanol with water and ammonia dominate the chemistry of cometary bodies, leftovers of the building blocks of the outer planets. We have previously determined the... -
New CO2-philic surfactants
The proposal aims to explore water-in-CO2 (w/c) microemulsions with new, very promising hydrocarbon surfactants. The compounds are generated using standard chemistry1 but with... -
Structure and phase transitions of Sr3Ru2O7
Sr3Ru2O7 is a layered Ruddlesden-Popper perovskite which displays intriguing behaviour at low temperatures and high magnetic field. It can be tuned close to a quantum critical... -
In Situ High Pressure NMR study of the Direct Synthesis of NaAlH4
NaAlH4 has been a model system for metal hydride hydrogen storage materials since the reaction was identified to be reversible. The decomposition pathway has been described by a... -
Pressure-induced proton migration in an energetic co-crystal
The results of these studies will provide valuable information on the effects of extreme conditions on the structures of an energetic salt and co-crystal formed between... -
Programme Access Rosseinsky
This dataset has no description
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Molecular Mechanisms of Enhanced Thermal Conductivity in Copper-based Nanofluids
The combination of the transport properties of liquids with the high thermal conductivity of metals is a promising way of improving heat transfer efficiency and thus reduce... -
Unpicking the signal of partial order from thermal motion in diffuse scatteri...
Orientationally-disordered water molecules in ice adopt a degree of partial order upon cooling, a process that is halted by kinetics at ~100 K in pure ice and ~60 K in KOH-doped... -
In-situ Hydrogenation of Calcium Nitride
Nitrides of alkali and alkaline earth metals are an interesting set of materials specifically for their potential in reversible hydrogen storage. However, many fundamental... -
Understanding the decomposition of ammonia by lithium-calcium imide
Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data... -
Identifying the muon site in fluorine containing compounds
Fluorides form model systems with which we can test ideas about muon sites. We therefore propose a series of short experiments on well-defined fluoride systems that will be... -
In situ studies of mixed-phase oxygen transport membranes
The oxygen transport membrane is a system being developed by St Andrews in conjunction with industry, which at high temperatures will allow the selective migration of oxygen... -
Inelastic neutron scattering investigation of Mg-K-phosphate cements reaction...
Mg-K phosphate cements (MPC) are used for nuclear waste encapsulation, bone repair, and in civil engineering. The chemical nature of the first amorphous reaction product is... -
Operando Analysis of Lithium/Sulfur Cells with SANS and deuterated solvents
Lithium sulfur (Li/S) batteries have a fivefold higher theoretical gravimetric energy density (2680 Wh/kgsulfur) than state-of-the-art lithium ion batteries. However, the strong... -
The mechanism of lipid transport in Gram-negative bacteria
The bacterial cell envelope is one of the best targets for antimicrobial development. It is this envelope that harbours the instruments of microbial warfare, preventing its... -
Quasielastic scattering in stuffed spin ices: defects or low lying singlets?
The subjects of this proposal, Ho2+xTi2-xO7-x/2, are brand new materials1 related to Ho2Ti2O7, a spin ice2,3. They have the remarkable property of remaining disordered at very... -
Thermal expansion of persubstituited aromatics I: benzene.
Benzene is probably the most studied compound in the history of organic chemistry. Whenever a new experimental technique or theoretical method is being developed most of the...
