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In-situ studies of alkaline earth nitride deuterides
Heavy alkaline earth nitride hydrides (AE2NH, with AE = Ca and Ba) are of interest due to their potential suitability as electrolyte materials in a variety of electrochemical... -
Investigation of the pressure dependence of the negative area expansion mater...
We will investigate the structure of 4-chloroimidazole a material, which undergoes extreme anisotropic thermal expansion,.as a function of pressure at a range of temperatures... -
Gas-phase oxidation of insoluble monolayer at air-water interface with no equ...
The Earth¿s climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects cloud droplet size and optical properties, important climatic... -
Towards the development of lithium manganese nitride as novel two stage regen...
In the last decades the production and consumption of reactive nitrogen increased exponentially due to the extensive utilisation of nitrogen containing compounds as fertilizers... -
Structural origin of anomalous relaxation behaviour in alcohol-water mixtures
In recent dielectric and calorimetric studies of some alcohol-water mixtures we have discovered unexpected and unexplained relaxation behaviours. Our aim with this proposal is... -
In-situ Neutron Diffraction Studies of Lithium Battery Materials
This proposal seeks to test a new battery designed to allow in situ neutron diffraction measurements of lithium ion battery electrodes under charge and discharge. We have... -
Investigation of a frustrated quantum magnet with novel interaction scheme
SrCuTe2O6 consists of a 3-dimensional arrangement of spin-1/2 Cu ions that are coupled into network of isolated triangles,a highly frustrated hyperkagome lattice consisting of... -
Decomposition studies of Li(1-x)NaxND2, LiNa2(ND2)3 and Li3Na(ND2)4
We ask for 3 days on GEM to study in-situ the decomposition of the Na-substituted LiNH2 phases, Li1-xNaxND2, LiNa2(ND2)3, Li3Na(ND2)4 and their reactions with LiD. LiNH2 is the... -
In situ studies of mixed-phase oxygen transport membranes
The oxygen transport membrane is a system being developed by St Andrews in conjunction with industry, which at high temperatures will allow the selective migration of oxygen... -
Time Resolved Studies on Inorganic Film Formation at the Air-Solution Interface
In a recent SURF experiment on the formation of silica films templated with cat-anionic/polymer complexes we found that the film growth and evolution occurs on a faster time... -
Pd, Ni, V, Nb and Ti capping layer clamping effects in hydrogen cycling in Ca...
We ask for 8 days of beam time on CRISP to study the absorption and desorption of hydrogen and deuterium in Ti/Mg/Pd trilayer samples. Our specific objective is to understand in... -
High Temperature Micromechanics Ni-based Superalloys: Creep, Stress Relaxatio...
In this study, in-situ high-temperature loading investigations will be performed to characterise the micromechanics of a high strength alloy 720Li, during stress relaxation in... -
Proton diffusion in lithium imide: a quasi-elastic neutron scattering study
Li_2NH has been recently considered for H_2 storage applications. However, its low-T crystal structure is still controversial, with at least 6 options compatible with the... -
Temperature driven spin incoherence and criticality in the Luttinger liquid p...
We propose an experiment on the low energy spectrometer LET to study temperature effects on the Luttinger liquid (LL) phase on the spin ladder geometry. The spin ladder material... -
Kinetics of the ordering transition in ice Ih; crystal structure and thermal ...
Below 80 K ordinary water ice (ice Ih) undergoes a phase transition in which the randomly oriented molecules in the crystal adopt an ordered orientation. This ordered form of... -
One- and multi-magnon excitations in a strong-leg quantum spin ladder
We propose to measure the one- and multi-magnon excitations in the first realization of a S=1/2 quantum spin ladder in the strong-leg regime. Our material, DIMPY, has very well... -
Higher resolution inspection of the hydrocarbon pool connected with the metha...
The reaction of methanol to form hydrocarbons over zeolite catalysts is an important option for conversion of natural gas or coal to liquid fuels. We have shown previously via... -
Simultaneous Microwave Dielectric Spectroscopy and Neutron Diffraction Measur...
Ammonia has been proposed as a high density chemical energy-storage media, which can be safely and reversible stored within low cost saline halides. Here we propose to extend... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
Building a comprehensive understanding of cation ordering in the commercial c...
The objective of the proposed experiment is to develop an understanding of the Li/Ni/Mn ordering in a commercially relevant lithium ion battery positive electrode,...
