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Decomposition studies of Li(1-x)NaxND2, LiNa2(ND2)3 and Li3Na(ND2)4
We ask for 3 days on GEM to study in-situ the decomposition of the Na-substituted LiNH2 phases, Li1-xNaxND2, LiNa2(ND2)3, Li3Na(ND2)4 and their reactions with LiD. LiNH2 is the... -
Investigation of a frustrated quantum magnet with novel interaction scheme
SrCuTe2O6 consists of a 3-dimensional arrangement of spin-1/2 Cu ions that are coupled into network of isolated triangles,a highly frustrated hyperkagome lattice consisting of... -
In-situ studies of alkaline earth nitride deuterides
Heavy alkaline earth nitride hydrides (AE2NH, with AE = Ca and Ba) are of interest due to their potential suitability as electrolyte materials in a variety of electrochemical... -
Programme Access Rosseinsky/Claridge
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Investigating the formation of novel mixed amide-imide complexes and understa...
Inexpensive light-metal amides are among the most highly active and effective ammonia decomposition catalysts at modest temperatures and are likely to surpass the performance of... -
Test of a New Supercritical In-Situ Hydrothermal Cell
The objectives of this proposal is to seek 2 days on POLARIS in order to test and complete a full commissioning of the latest design of our prototype in-situ reaction cell for... -
Investigation of a Potential realization of the Nersesyan-Tsvelik Model in (N...
We propose to investigate the highly one-dimensional (1D) S=1/2 Heisenberg antiferromagnet (NO)[Cu(NO3)3] which is a potential realization of the Nersesyan-Tsvelik model. The... -
In-situ Thermoelectric Measurements of Copper Iron Sulphides
Thermoelectric devices are capable of converting thermal energy directly into electrical energy. Large-scale applications of the technology requires materials that are composed... -
Sensing SO2 in Robust Porous MOF Materials via Simultaneous Microwave Dielect...
We seek to develop new MOFs for sensing and removal of toxic gases (e.g., SO2) and request 4 days on POLARIS to study the structural binding details and dielectric data... -
Simltaneous dielectric spectroscopy and neutron diffraction
We have constructed a novel microwave frequency resonator that can sit within the GEM and POLARIS diffractometers and will allow us to simultaneously collect diffraction and... -
Formation and ammonia decomposition behaviour of lithium nitride hydride
Ammonia is seen as a key part of the transition to a sustainable energy economy, but needs decomposition catalysts to release its stored hydrogen. Lithium nitride-hydride... -
Crystal and magnetic structures of mixed-valent V2OPO4
The electronic states of transition metal oxides usually result from a coupling between the three degrees of freedom: charge, orbital and spin states. When metal-metal distances... -
In-situ reaction of lithium amide or imide with manganese(IV) oxide
We request 3 days beam time on POLARIS for in-situ powder diffraction studies of the reactions of lithium amide or lithium imide with manganese(IV) oxide under flowing argon or... -
Search for structural modulation lifting the orbital degeneracy in triangular...
This proposal is part of our research programme on spin and orbital order in frustrated systems. AgNiO2 has a layered crystal structure with Jahn-Teller active Ni3+ ions forming... -
Ionic mobility in soggy sand electrolytes
Ionic liquids (ILs) are gaining increased interest as electrolytes given their thermal and chemical stability, wide electrochemical windows, and ionic conductivities. However,... -
Quantum critical points in relaxor-type ferroelectric tetragonal tungsten bro...
Quantum Critical Points in ferroelectrics, where the transition temperature is very near absolute zero, are of significant current interest, with publications in Nature-family... -
POLYMORPHISM IN PLATINUM(II) COMPLEXES PROBED BY SIMULTANEOUS INS AND RAMAN S...
The present study aims to probe polymorphic transitions in Pt(II)-amine complexes, aiming at identifying the INS and Raman spectral signature of each species as well as their...