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Hydrogen storage: interaction between hydrogen and lithium nitride at high pr...
We apply for beam time on TOSCA to investigate this highly unusual system. Lithium nitride appears unique among storage materials in its ability to take up significant amounts... -
The Dynamics of Molecular Hydrogen in Synthetic Clays
In this proposal we aim to study the low temperature uptake and dynamics of hydrogen in the interlayer region of partially hydrated pillared clays. There are linked dual... -
Determination of the Pt-H bondlengths on a Pt/C fuel cell catalyst
We have recently demonstrated that it is possible to obtain structural information about adsorbed hydrogenous species from a variety of metal catalysts. We emphasise that this... -
Metal decorated graphene for Hydrogen Storage
Previous uSR measurements on chemically produced graphene showed that, apart from a slowly relaxing graphite-like fraction, approximately 40% of the implanted muons are trapped... -
Hydrogen Uptake by Pillared Graphite Oxides
High sorption capacities and enhanced interaction strengths are the two most fundamental prerequisites for the deployment of carbon-based materials as hydrogen-storage media. In... -
Diffusional Dynamics of Molecular Hydrogen Bound to Carbon Nanohorns
The present experiment aims to elucidate the energetics and geometry of translational diffusive motions exhibited by molecular hydrogen bound to carbon nanohorns. Previous... -
A comparative analysis of state-of-the-art reconstruction methods applied to ...
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Copy of: IINS Study of the Molecular Properties of Hydrogen Peroxide/Water Mi...
Hydrogen Peroxide is one of the cleanest, most versatile strategic base chemicals available. It is used at the large scale as oxidising agent in the chemical industry, as a... -
Hydrogen Release Systems: MX2.(NH3)n (M=Mg, X=Cl) with LiH and MgH2
The applicants seek 3 days of beam time on POLARIS to study hydrogen release systems comprising M(NH3)6X2 (M=Mg, X=Cl) coupled with LiH and MgH. Mg(NH3)6Cl2 is an important... -
Hydrogen dynamics in clay nanotubes
We will study H2 dynamics in the nanotubular clay imogolite whose structure has an external diameter of ~2.5 nm and an inner diameter of <1 nm. The tube length of synthetic... -
Structure of Molecular Hydrogen in Synthetic Laponite Clay Hydrates
In this proposal we aim to study low temperature structure of hydrogen in the interlayer region of partially hydrated pillared clays. There are linked dual motivations for this... -
Simultaneous INS and Raman spectra of centropolyindanes.
The family of centropolyindanes are created by edge-wise fusing of the cyclopentane ring of several indane units (D. Kuck, Chemical Reviews 2006, 106, 4885-4925).... -
Coordinated, Recoiling Molecules Tethered by Hydrogen Bonding: Ammonia in Zeo...
We request 5 days on IRIS to investigate the hindrance to molecular rotation of ammonia in a zeolite framework due to hydrogen bonding interactions. This is a tied proposal to... -
Hydrogen bonds as synthons in novel molecular magnets
Many strategies have emerged in recent years in the quest to design and synthesize functional materials which show cooperative properties. A particularly successful route to new... -
In-situ Inelastic Neutron Spectroscopy Studies Of Magnesium Tetrahydroborate ...
The development of high energy density and high efficiency hydrogen storage materials is widely considered to be one of the most challenging barriers to the adoption of fuel... -
Neutron Diffraction Studies of Halide-Modified Amide Hydrogen Storage Materials
The aim of this proposal is to use neutron powder diffraction to characterise a series of 9 new halide modified lithium amides and imides which are of interest as reversible... -
Hydrogen bonding in amorphous formic acid
Formic Acid (FA) is a simple model for rotational isomerism, and it presents four different hydrogen bonding sites. In a recent study, we have elucidated the structure of FA in... -
Hydrogen diffusion in novel porous carbon materials for fuel cells
The performance of polymer electrolyte fuel cells (PEMFC) is strongly dependent on the diffusion rate of hydrogen and the electron mobility, which in turn is strongly influenced... -
Hydrogen activation by non-metal catalysts. IINS studies of Frustrated Lewis ...
Hydrogenation has played a crucial role in energy related applications ranging from the production of ammonia from N2 to the conversion of coal to liquid fuels. Until recently,... -
Kinetics of Hydrogen Abstraction by Mu Reactivity with Propane studied by RF ...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit...