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Graphite Oxide Intercalation: Tailoring Adsorbate Geometry
The search for new porous materials is increasingly driven by a socio-economic pressure to diversify our energy supply and minimize environmental impact. Carbon-based... -
Mapping water dynamics in icy carbonaceous environments
Polycyclic aromatic hydrocarbons (PAHs), a wide class of organic molecules with multiply fusedaromatic rings, are ubiquitous in the interstellar medium. In the condensed phase... -
Unveiling the role of phonons in reaching very high blocking temperatures in ...
One of the main goals of the research in Molecular Magnetism is to increase the blocking temperature TB of Single-Molecule Magnets (SMMs). A significant breakthrough was... -
Crystal field excitations in SrTb2O4
SrTb2O4 belongs to the family of rare-earth RE strontium oxides, SrRE2O4. These compounds, consisting of hexagons and triangles, are affected by geometrical frustration and... -
INS Study of Bio-oil on a Hydrodeoxygenation Catalyst
The Indonesian government has recently passed a new policy regarding a mandatory regulation for all gas stations nationwide to replace existing diesel fuel to B-20 biofuel.... -
Towards understanding hydrogen defects in perdeuterated systems
The use of deuteration to overcome the difficulties associated with the incoherent scattering from hydrogen, is a well established technique. However, there are increasing... -
Which is it? ¿ Neutrons distinguish monolayers xrays can¿t.
We have obtained the monolayer structure diffraction patterns from several iodoalkanes adsorbed on graphite, of interest in the study of non-covalent bonding. However, it is... -
Complex Magnetism in Cobalt-Rhenium Double Perovskites
We have recently been studying a series of rhenium-cobalt oxide phases, based on the cation deficient perovskite phase Ba4Re2CoO12. Lithium can be inserted into the vacant sites... -
Neutron diffraction investigation of magnetic correlations in the S= 1/2 trim...
Spin-trimer chain systems are of current interest due to unconventional properties arising from the strong quantum fluctuations and topology, such as the occurrence of the... -
Search for new hydrogen, helium and neon hydrates at high pressure
This proposal is for time to search for predicted gas hydrates at high pressure. The results will provide insight into the factors governing the stability of the H-bonded... -
Investigation of crystal field excitations in RRh3 (R=Pr and Nd) compounds
To determine the crystal fields of hexagonal RRh3 (R=Pr, Nd) compounds showing ferromagnetic transitions at TC=3 and 6 K, respectively, we plan to perform inelastic neutron... -
Crystal field excitations on Sm based pyrochlores
The A2B2O7 pyrochlore family, where A is a rare earth ion and B=Ti, Sn, is one of the most prolific series of compounds presenting magnetic frustration. The geometric Fd-3m... -
High energy spin excitation in superconducting Rb0.8Fe1.68Se2
Superconductivity (SC) in unconventional superconductors is believed to be related to magnetism. However, in AyFe1.6+xSe2 (A = K, Rb, Cs) system discovered in late 2010, the SC... -
Structural and Magnetic Properties from Charge Orders in Iron Perovskite Oxides
Highly oxidized transition metal cations in oxides tend to display unusual electronic and magnetic behavior due to the highly covalent nature of the M-O interactions. Iron is of... -
QENS Studies of Diffusion of NH3 Molecules in Porous MOF Materials
The development of new porous metal-organic frameworks (MOFs) is receiving considerable attention worldwide owing to their potential for gas storage, separation, and... -
Exploring lattice dynamics in giant barocaloric (NH4)2SO4 under pressure
Cooling is at the heart of modern technology, from storing and transporting food and medicine to computing. Yet current refrigeration technologies rely heavily on... -
Spin-Driven Multiferroics CdMn7O12 and SrMn7O12
We propose to perform neutron diffraction experiments on powder samples of possible spin-induced multiferroic materials, 114CdMn7O12 and SrMn7O12, at ambient pressure and low... -
Understanding high-performance light-emitting diodes based on carbene-metal-a...
The technology of organic electronics unlocks new ways to create semiconductor devices which are impossible using more conventional materials. The organic semiconductors at... -
Distinguishing OH and F in Framework Materials
Our recent work using fluoro- starting materials in fluoro-media in combination with framework forming species such as T(O,F, OH)n (T = Si, P, B and other tetrahedral-forming... -
Wittig Revisited: Cleaning up 50 years of Waste in Metal-Free Catalysis
Recent thereotical determinations on the Wittig reaction point to low energy (terahertz) vibrations in the ~15-50 meV region being responsible for selectivity of this industrial...
