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Magnetic structure and multiferroicity in metal-formate perovskites
The family of guanadinium metal formates (M=Mn, Fe, Co, Ni, Cu) are isostructural with the perovskites and are therefore of interest for potential applications: in particular,... -
Magnetism and structural distortions in the Sr(2-x)Ba(x)NiOsO6 system
The magnetism of double perovskites can be amazingly sensitive to subtle distortions of their structures. Previous studies have shown that Ca2NiOsO6 is a ferrimagnet, Sr2NiOsO6... -
Inelastic neutron scattering study of the antiferromagnetic triangular system...
We propose to study the temperature dependence of the inelastic response of BaCoO3. This system gives the experimental evidence of a new partially disordered antiferromagnetic... -
Superconductivity and critical spin fluctuations
In a successful recent experiment on IN5 (ILL), we have been able to show that in contrast to commonly accepted wisdom, the excitation gap in nearly optimally doped... -
Study of magnetic spiral in the room temperature multiferroic BiFeO3 - PbTiO3
BiFeO3 is a room temperature multiferroic, displaying both ferroelectric and antiferromagnetic (AFE) ordering. x-BiFeO3 - (1-x)-PbTiO3 is also multiferroic at room temperature... -
Effects of external and chemical pressure on the magnetovolume effects in Ba3...
Ba3BiIr2O9 and Ba3BiRu2O9 undergo very unusual structural transitions at 74 and 176 K respectively, with instantaneous negative thermal expansion of up to 1% in the Ir compound.... -
Understanding the ground state wavefunction in PrPtAl and YbNiSn
The proposal addreses the compounds PrPtAl and YbNiSn. Both systems are canted ferromagnets with both materials undergoing moment reorientation transitions as a function of... -
The structural phase transitions of Ammonia Borane, an invetigation of the dy...
Ammonia Borane (AB), NH3BH3, was first synthesised in the 1950s and has now become the focus of a world wide research program with regards to its potential as a hydrogen store.... -
Structure and phase transitions of Sr3Ru2O7
Sr3Ru2O7 is a layered Ruddlesden-Popper perovskite which displays intriguing behaviour at low temperatures and high magnetic field. It can be tuned close to a quantum critical... -
In situ Investigation of the Locations of Gas Molecules within a Decorated Po...
In the coming year, we plan to build upon the success of last cycle by carrying out more hydrocarbon studies of this porous material NOTT-300 and one of its iso-structural... -
Multiferroic (Ferroelastic/Magnetic) Phase Transitions in KMnF3
KMnF3 perovskite undergoes 3 structural, and two magnetic phase transitions on cooling from 300 K to 2 K. Above 185 K the compound is in the aristotype structure, on cooling... -
Low-Temperature Structural Phase Transitions in GeV4S8
The defect thiospinel, GeV4S8 adopts a cubic structure at room temperature (space group F-43m). We have identified a new monoclinic phase of this material at 2K, which may be... -
Determination of the low temperature Crystallographic and magnetic structures...
TlCoCl3 and Tl FeCl3 undergo structural phase transition at T1= 165K, respectively T1= 179K and T2=75 K, respectively 79 K. The unit cell stay hexagonal but the basic unitcell... -
Vibrational properties of Vanadium and Zirconium based metal hydrides
Inelastic neutron scattering has proven to be reliable tool to investigate the phonon structure of hydrides. E.g., it was shown that the vibrational structure of Ca(BH4)2 has a... -
Study of spin wave and crystal field effect in R2RuO5 (R = Pr, Nd, Tb
R2RuO5 (R = Pr, Nd, Sm, Gd, Tb) are known to exhibit interesting physical properties. They all show magnetic ordering between 8 ¿ 24 K. They also show large Sommerfeld... -
A Self-consistent Description of the Thermoelastic Properties of Dielectric P...
20 years ago, Anderson proposed that the thermoelastic properties of the dominant (mantle) phase within the Earth, MgSiO3 perovskite, could be described as a simple Debye solid.... -
Short and long-ranged magnetic order in the new isotropic S = 1/2 kagome ferr...
Exotic electronic states are of great interest to fundamental science, such as the quantum spin-liquids (QSLs) which were theorised to behave like a sea of resonating spin... -
Strain analysis of commensurate charge order/zener polaron ordering transitio...
High resolution powder diffraction data will be used to obtain lattice parameter and atomic coordinate variations as a function of temperature for Pr0.6Ca0.4MnO3, which has a... -
Magnetic structure of pyrochlore irridate Y2Ir2O7
We propose to study by powder neutron diffraction the ordered magnetic state of the pyrochlore compound Y2Ir2O7. There is currently an increasing interest in the condensed... -
Inelastic Neutron Scattering (TOSCA ) Studies of Mordenite Catalysts for the ...
This proposal will measure vibrational spectra from a series of catalyst samples produced from a pilot plant reactor at Tianjin University China converting dimethylether to...
