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High pressure charge transitions in PbCoO3
PbCoO3 used to be the missing link in the PbMO3 perovskite series. PbCoO3 was recently synthesized by the Azuma group using high-pressure synthesis at 12 GPa. NPD at JPARC... -
Does the viscosity of the sub-phase effect the oxidation kinetics of surface ...
Atmospheric climate change is strongly influenced by clouds and the oxidative processing of pollutants in clouds affects droplet size and reflectivity of the planet. Clouds... -
The Location of Guests in Metal-Organic Frameworks Using IINS
Metal-organic framework materials are a topical family of nanoporous solids that have potential applications in molecular storage, separation and catalysis. This includes the... -
In Situ High Pressure NMR study of the Direct Synthesis of NaAlH4
NaAlH4 has been a model system for metal hydride hydrogen storage materials since the reaction was identified to be reversible. The decomposition pathway has been described by a... -
Comparison of the Compression Behaviour of BaSnO3 and Ba0.575Sr0.425SnO3
We propose to study the effect of pressure on the structure of the tetragonal Ba0.575Sr0.425SnO3, The behaviour will be compared to the compression of the cubic BaSnO3 (parent... -
Unpicking the signal of partial order from thermal motion in diffuse scatteri...
Orientationally-disordered water molecules in ice adopt a degree of partial order upon cooling, a process that is halted by kinetics at ~100 K in pure ice and ~60 K in KOH-doped... -
In-situ Hydrogenation of Calcium Nitride
Nitrides of alkali and alkaline earth metals are an interesting set of materials specifically for their potential in reversible hydrogen storage. However, many fundamental... -
Understanding the decomposition of ammonia by lithium-calcium imide
Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data... -
In situ studies of mixed-phase oxygen transport membranes
The oxygen transport membrane is a system being developed by St Andrews in conjunction with industry, which at high temperatures will allow the selective migration of oxygen... -
Investigation of glycolide-h4 and d4 at high pressure.
This proposal seeks to investigate the polymorphism and polymerisation of glycolide. Glycolide is a six-memebered ring structure that polymerises into poly(glycolic acid) and is... -
Self-Assembled Atmospheric Fatty Acid Aerosol Proxies: Spin-Coated Thin Film ...
We propose a simultaneous neutron reflectometry (NR)/attenuated total reflection (ATR) infra-red spectroscopy experiment on spin-coated thin films of self-assembled fatty acids... -
Structural evidence of lipopolysaccharides functioning as receptors in antimi...
The global increase of bacterial resistance to antibiotics has led to increasing interest in research focusing on the development and characterization of new antimicrobial... -
Operando Analysis of Lithium/Sulfur Cells with SANS and deuterated solvents
Lithium sulfur (Li/S) batteries have a fivefold higher theoretical gravimetric energy density (2680 Wh/kgsulfur) than state-of-the-art lithium ion batteries. However, the strong... -
pH-control of swelling and charge neutralization of thin hydrogel films
Hydrogels are widely used in biomaterials science, much due to excellent protein resistance, and physicochemical properties similar to biological tissue. Charge neutrality is... -
Ultrafast motion of molecular rotors in metal-organic frameworks: a muon-spin...
In recent years, amphidynamic crystals have gained more and more attention as a state of matter somehow intermediate between solids and liquids. In fact, although these systems... -
Do hydroxyl radicals penetrate the organic monolayer at the air-water interface?
The Earth¿s climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects droplet size and optical properties, important climatic effects.... -
Quasielastic scattering in stuffed spin ices: defects or low lying singlets?
The subjects of this proposal, Ho2+xTi2-xO7-x/2, are brand new materials1 related to Ho2Ti2O7, a spin ice2,3. They have the remarkable property of remaining disordered at very... -
Me-ND311BD4: a temperature dependent study of its crystal structure and decom...
We request 4 days on HRPD with the IGAn apparatus to follow the structural changes of Me-ND4 11BD4 as a function of temperature. The high resolution of HRPD will allow us to... -
H2O transport into the deep Earth: A high P-T study of hydrous Phase-A
The mantle is estimated to be planet Earths most massive volatile (e.g. H, C, S, N) storage reservoir, with interactions between crustal and mantle reservoirs dominate the... -
Self-assembled Floating Lipid Bilayers: What Forces Are Causing the Bilayer t...
Recently (RB19100102) we have discovered that floating bilayers composed of fluid phase lipids can be produced by deposited vesicles onto charge modified oligo(ethylene...
