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Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and... -
Sensing Sulphur Dioxide in Robust Porous MOF Materials via Simultaneous Micro...
We seek to develop new materials for sensing and removal of toxic gases (esp., SO2) and request 2 days on POLARIS to study the structural binding details and dielectric data... -
The possibility of strongly ferromagnetic austenite in a stainless steel
It is generally accepted that austenitic steels (fcc) show no ferromagnetic signature. However, thermomagnetic measurements suggest an unexpected ferromagnetic transition (Tc =... -
Order/disorder and phase transitions in the OLED material Alq3
We propose to measure the pair distribution function of the organic light emitting material Alq3 focussing on the structure of one disordered crystalline phase and its... -
Spatial, Chemical, and Temporal Resolution of Platinum-Catalysed Benzene Conv...
This proposal aims to study the potential for neutron diffraction to offer spatially-, chemically-, and temporally-resolved information on a dynamic system, in this case the... -
In-situ mechanistic studies of hydrogen storage reactions in lithium amide ha...
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Hydrogen production from ammonia using lithium imide: an isotope study
We have recently discovered that light metal amides and imides are excellent cattalysts for the decomposition of ammonia. We request 3 days on POLARIS to perform in situ neutron... -
Crystal symmetry change at the magnetic transition in MnB and FeB compounds p...
The "magnetocaloric effect" (MCE) is based on the entropy difference encountered when themagnetic state of a material is changed and it can be used for refrigeration. However,... -
Magnetic excitation spectrum of a potential spin liquid candidate
PbCuTe2O6 consists of a 3-dimensional arrangement of spin-1/2 Cu ions. There are 3 potentially strong interactions, the first neighbor interaction couples the magnetic ions into... -
Understanding the decomposition of ammonia by lithium-calcium imide
Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data... -
In Situ High Pressure NMR study of the Direct Synthesis of NaAlH4
NaAlH4 has been a model system for metal hydride hydrogen storage materials since the reaction was identified to be reversible. The decomposition pathway has been described by a... -
Structure and Phase Transitions of XNbOP2O7, with X = ND4 and Rb
In this proposal we request 3 days of beam time on HRPD to study the structure and phase transitions of XNbOP2O7 (X = Rb and ND4). These materials have been shown to undergo... -
In-situ hydrogen decomposition studies of ammonia borane and the diammoniate ...
Ammonia borane (AB) is one of the most promising hydrogen storage materials. We have extensively studied the low temperature behaviour of this material This proposal asks for 3... -
Thermoelastic Properties of Thermoelectric PbSe I HRPD
We propose to study the effect of pressure and temperature on the crystal structure and the elastic properties of lead selenide, an important material for conversion of waste... -
In-situ thermoelectric measurements of copper chalcogenides
Thermoelectric devices are capable of converting thermal energy directly into electrical energy. The efficiency of a device is related to the characteristics of the materials of...