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Influence of Zeolite Structure on propane/propene separation from mixtures us...
Zeolites are perhaps the most successful microporous materials used for catalysis and separation processes in refineries and chemical industries[1-3]. This is due to the... -
The crystal structure of multiferroic CuO
Despite its simple chemical formula, cupric oxide (CuO) has a surprisingly complex magnetic behaviour which remains only partly understood. Interest in CuO has recently... -
Investigating the diffusion component of the toluene hydrogenation reaction i...
The diffusion of hydrocarbons relevant to the toluene hydrogenation reaction will be measured both as unconfined liquids and confined in the catalyst Pt/MCM-41. Diffusion will... -
In-situ neutron powder diffraction studies of non-stoichiometry in Na battery...
We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium... -
In-situ diffraction studies of ammonia decomposition over iron, ruthenium and...
We request 3 days beam time on POLARIS for the in-situ study of the crystalline phase composition of iron, manganese and ruthenium catalysts for ammonia decomposition. These... -
Combined in-situ structural and hydrogen desorption/absorption studies of hyd...
The Li?N?H hydrogen storage system is one of the most promising candidates for hydrogen storage in vehicular applications and the addition of halide ions significantly increases... -
Reflectometry studies of the mechanism of formation of mesoporous silicate fi...
Surfactant-silica self-assembly processes have been extensively studied since the discovery of M41S mesoporous materials in 1992. Mesoporous silicate films can be grown from... -
Structural studies of thermochemical and phase-change naterials for heat storage
This proposal seeks to study three systems associated with heat-storage applications using in situ neutron powder diffraction. The first experiment will focus on a sample of... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
Building a comprehensive understanding of cation ordering in the commercial c...
The objective of the proposed experiment is to develop an understanding of the Li/Ni/Mn ordering in a commercially relevant lithium ion battery positive electrode,... -
Simultaneous Microwave Dielectric Spectroscopy and Neutron Diffraction Measur...
Ammonia has been proposed as a high density chemical energy-storage media, which can be safely and reversible stored within low cost saline halides. Here we propose to extend... -
Study of pore-confined CO2 depletion below the bulk triple point
Freezing of fluids confined at the nanoscale is of great importance for the understanding of their behaviour due to the confinement effects arising from the finite pore size and... -
Investigation of a frustrated quantum magnet with novel interaction scheme
SrCuTe2O6 consists of a 3-dimensional arrangement of spin-1/2 Cu ions that are coupled into network of isolated triangles,a highly frustrated hyperkagome lattice consisting of... -
In-situ studies of alkaline earth nitride deuterides
Heavy alkaline earth nitride hydrides (AE2NH, with AE = Ca and Ba) are of interest due to their potential suitability as electrolyte materials in a variety of electrochemical... -
Investigating the formation of novel mixed amide-imide complexes and understa...
Inexpensive light-metal amides are among the most highly active and effective ammonia decomposition catalysts at modest temperatures and are likely to surpass the performance of... -
Monitoring Gamma Prime Evolution in Superalloys using Small Angle Neutron Sca...
The aim of the experiment is to monitor the temporal evolution of gamma prime precipitates in three polycrystalline nickel base superalloys using Sans2D. This instrument is... -
Test of a New Supercritical In-Situ Hydrothermal Cell
The objectives of this proposal is to seek 2 days on POLARIS in order to test and complete a full commissioning of the latest design of our prototype in-situ reaction cell for... -
Investigation of a Potential realization of the Nersesyan-Tsvelik Model in (N...
We propose to investigate the highly one-dimensional (1D) S=1/2 Heisenberg antiferromagnet (NO)[Cu(NO3)3] which is a potential realization of the Nersesyan-Tsvelik model. The... -
In-Situ Studies of Alternative Mobile-Ions for High-Temperature Thermal Batte...
Whilst rechargeable batteries continue to take over the consumer electronics market, they are unsuitable to replace specific battery technologies, such as the thermal battery,... -
Low-energy magnetic excitations in the superconducting state of Sr2RuO4: open...
We propose to study the magnetic fluctuations of the unconventional superconductor Sr2RuO4 in the superconducting state extending our previous experiments on a cold triple-axis...