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The Structure of Lead Tungstate-Phosphate Glasses
Lead tungstate phosphate glasses are of practical interest due to their electrochromic and photochromic properties, with a wide range of practical applications in smart windows,... -
Structure and dynamics of quartz-like metal-organic frameworks (MOFs)
As part of an ongoing effort to understand the underlying physics of MOFs, we propose to study the local structure and dynamics in two quartz-like systems: indium deuterium... -
The structure of LiPON and NaPON glass
Lithium (LiPO3) and sodium (NaPO3) metaphosphate glasses show improved ionic conductivity when some of the oxygen in the phosphate tetrahedron is replaced by nitrogen. As such... -
The Nature Of Magnesium Substitution in Beta-Tricalcium Phosphate
We have a long established interest in the materials used for the immobilisation of nuclear waste from the domestic power industry and legacy waste from various defence... -
How molecular solids prepare for phase transitions: The phase transition in o...
Oxalyl chloride (mpt. 260 K), forms an ordered phase at low temperature, but a disordered phase between 250 K and the melting point. In previous beamtime we aimed to carry out... -
Structural investigation of biodegradable Mg-based bulk metallic glass
Mg-Zn-Ca glasses show considerable promise for use as medical implants. Magnesium, zinc and calcium are all elements found within the human body, and the biocompatibility of... -
Effects of Local Displacements on Phase Transitions in Sr- and Ca-substituted...
Ferroelectric BaTiO3 (BT) constitutes a base system for many practical applications ranging from classical capacitors to tunable dielectrics. A dielectric response in BT is... -
The structure and hydrogen bonding of poly(pyridobisimidazole) (PIPD)
PIPD is a polymer with unusual tensile and compressive strength. Inter and intramolecular H-bonding interactions are thought to be responsible for these properties. PIPD is also... -
Understanding composition-driven anomalous tetragonality in a ferroelectric s...
The primary aim of this proposal to investigate a series of newly discovered Bi- containing ferroelectric systems based on Bi(MeMe)O3-PbTiO3 perovskite through studying their... -
Copy of: Local magnetic order and the paramagnetic-parmagnetic transition in MnO
The antiferromagnetic-paramagnetic transition in MnO at 118 K occurs at a much lower temperature than anticipated from its Curie-Weiss constant theta~550 K. Consequently, strong... -
Investigation of the Negative Thermal Expansion in (Sr,Ca)FeO2 with FeO4 squa...
SrFeO2 bears a square planar oxygen coordination around Fe2+. The rarity of this structure led us to study the substitution of strontium by calcium and we obtained the solid... -
Preferential Conduction Pathways in Sodium Conducting Glasses for Battery App...
The ionic conductivity of sodium chalcogenide or chalcohalide glasses is 2 to 3 orders of magnitude higher than that of oxide glasses and comparable with lithium ionic... -
As2Ch3 glasses: Understanding the relationship between glass structure and no...
We wish to study a series of glasses of composition As2Ch3 (Ch = S, Se and Te) to investigate the effect of varying the chalcogen type on the non-linear optical (NLO) behaviour... -
Structure of novel silica-free titanate glasses
Silica-free barium titanate bulk glasses, containing lanthanide elements, show unusually high dielectric response and a high refractive index. These properties allow crucial... -
Structures of New Doped RuO2 Rutiles
We have prepared some new mixed-metal oxides using a chemical synthesis approach that provides access to materials not seen using other techniques. The materials are potentially... -
PDF analysis for the local structures of PZT in the morphotropic phase boundary
We request four days of GEM time to collect full patterns on PbZr1-xTixO3 (PZT) with different compositions at room temperature for Pair Distribution Functions (PDF) analysis.... -
The structure of hydrogen in calcium-ammonia-graphite: an in situ time resolv...
The aim of this proposal is to determine the in-plane and out-of-plane structure of H2 in the two dimensional galleries of stage-I calcium-ammonia-graphite intercalates: this... -
Structural changes in 320GB Blu-ray disc based on BiOx glass
Japanese company TDK has recently developed a 320GB optical storage disc. In contrast to usual DVDs and BDs, the 320GB TDK disc seems to operate because of difference in... -
The Dynamics of Breathing Metal-Organic Frameworks from Total Scattering
Metal-organic framework materials are a family of nanoporous solids that have potential applications in molecular storage, separation and catalysis. Some of these materials show... -
Understanding the relationship between glass composition and rare earth envir...
We wish to investigate the effect of glass composition on the environment of rare earth ions doped into chalcogenide glasses. To achieve this the series of glasses, yNd2S3 ¿...