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Multiscale time-resolving study of crystallisation in polyethyleneoxide
We will exploit the powerful and unique capability of NIMROD to follow in a time-resolving manner the crystallisation of polyethyleneoxide (PEO). There are three key length... -
In-situ studies of amides with ammonia
The aim of this proposal is to determine that materials that are present in the ammoniation of amides. -
Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and... -
Multiscale studies of crystallisation in synthetic polymers
We wish to exploit the unique capability of Nimrod to move forward the long standing issue of the way in which long chain polymers crystallise. For synthetic polymers there are... -
Structural insights into crude oil asphaltenes: A multi-parametric SANS/WANS ...
Asphaltenes are a complex and problematic fraction of crude oil that can precipitate, alter wettability and stabilise unwanted oil-in-water emulsions. Asphaltene molecules are... -
In-situ studies of thermal electrochemical cells utilising transition metal s...
Thermal batteries are used in applications were high reliability is a key requirement. They can be stored for decades and activated in less than a second. Most contemporary... -
QENS Investigation of Proton Conduction Mechanism in Spark-Plasma-Sintered Pr...
Fuel cells exhibit high-energy efficiency and the only release is clean water when used with hydrogen. Proton ceramic fuel cells (PCFC) are from special interest because proton... -
INS studies of Nafion and model compounds
In the archetypal hydrogenoxygen proton exchange membrane fuel cell design, a proton-conducting polymer membrane (typically Nafion) contains the electrolyte solution that... -
Ordering and interfaces in deuterated semiconducting liquid crystal/polymer s...
The main objective of this proposal is to study the structure of the interface between a semiconducting liquid crystal (LC) and a soft dielectric substrate for their potential... -
In-situ neutron powder diffraction studies of non-stoichiometry in Na battery...
We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium... -
Shear controlled crystallisation of low molar mass compound in a polymer matrix
The aim of this experiment is to explore a very recent discovery made by ourselves that shear flow can suppress the nucleation and growth of crystals of specific low molar mass... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
Towards the development of carbonitrides as novel two-stage regenerable reage...
We are examining a number of cobalt-molybdenum carbonitrides as possible catalysts for reactions that produce nitrogen-containing organic molecules. There is good evidence that... -
In-situ hydration and total scattering studies of Ba2In2-xMxO5 (M = Y and Ga)...
Motivated by the goal of improving the proton conduction in the brownmillerite Ba2In2O5 we are investigating the role of isovalent substitution at the indium sites. In... -
Oxygen mobility in the defect perovskite Sr3SbO5.5
We propose to use Polaris to record powder neutron diffraction data for the oxygen deficient double perovskite Sr3SbO5.5 as a function of temperature to establish the... -
In situ studies of mixed-phase oxygen transport membranes
The oxygen transport membrane is a system being developed by St Andrews in conjunction with industry, which at high temperatures will allow the selective migration of oxygen... -
QENS on Lightweight Borohydrides
We propose to study two aspects of the hydrogen dynamics in complex hydrides:First: The structural transitions in borohydrides are believed to be connected with an increase in... -
Free volume calibration of Polystyrene (PS) bulk above and below its glass tr...
Free volume theory has successfully predicted and described all of the liquid-to-solid transitions in hard sphere system. However, in polymer system, the exact molecular picture... -
Towards the development of lithium manganese nitride as novel two stage regen...
In the last decades the production and consumption of reactive nitrogen increased exponentially due to the extensive utilisation of nitrogen containing compounds as fertilizers... -
Structure of High Density and Low Density solid water
The hypothetical connection between liquid water and the two liquid phases: Low Density Liquid (LDL) and High Density Liquid (HDL) has been difficult to prove experimentally...
