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Isosymmetric Structural Changes in Y(Mn,Ti)O3
YMnO3 attracted significant attention because of its multiferroic properties and the "geometric origin" of its ferroelectricity. Despite numerous studies of this compound, the... -
Quantum Methyl Rotors for Gas Sensing in Zeolitic Imidazolate Framework-8
We aim to utilise Low-Energy Neutron Scattering (LENS) at OSIRIS to investigate the effects of gas adsorption on the quantum rotation of the methyl groups present in a Metal... -
Designing Porous Polymeric Gas Sensors
Porous polymer materials are important given their use in a wide variety of applications, for example detection of pollutants in the environment or security sensing of explosive... -
Oxidation of gram-negative cell-wall proxy with OH radicals - kinetics and me...
Hydroxyl radicals may be used as disinfection agent in the advanced oxidation processes or tertiary treatment of waste and occasionally drinking water. In this exploratory work,... -
Worm-like reversed micelles with a CO2-philic surfactant
Hydrotropes (Figure 3 A-C) are known viscosifying agents with surfactants in organic solvents1 and interestingly now in supercritical CO2 (scCO2)5. The mechanism is... -
Inelastic Neutron Scattering Analysis of Methoxy Motion in Functionalised Met...
Owing to the tuneable nature of metal-organic frameworks (MOFs), functionalisation is a common methodology employed to introduce active groups to the material for enhanced gas... -
Methane hydrate formation in the presence of surfactant
In this proposal we wish to study in situ formation of methane hydrates in surfactant solutions. The broad aim of this research is to enable us to understand how we can... -
From polymer molecular architecture to lubrication efficacy and CO2 emission ...
In collaboration with Infineum (a world-leading engine-oil additive company), we propose a SANS study of self-assembly of novel polymethacrylate (PMA) block copolymers as a... -
How muons see the motion of negative hydrogen ions in solids
Ions are often diffusing in solids. Among many ions, H+, Li+, Na+, O2-, and F- are known to become mobile at high temperatures in solids and they are used for fuel cells and... -
Residual Stress Measurement in Fibre Laser Beam Welded Aluminium Plates
Fibre Laser Beam Welding (FLBW) is a relatively new technology that has many advantages over other welding techniques. An understanding of the residual stress and... -
The effect of strain-path on the anisotropy of a dual phase steel
Steels often have anisotropic mechanical properties due to texture or internal stress generated by deformation. Recently it has become desirable to control this anisotropy, to... -
Optimal fluorination and structure of triple-fluorocarbon-tail surfactants fo...
This proposal aims to explore optimal fluorine (F) content and chain architecture in triple-fluorocarbon (FC)-tail surfactants used as CO2-philic solubilizers for water-in-CO2... -
Probing the viability of water-in-CO2 microemulsions with Headgroup-free amph...
Recent SANS studies of an unusual headgroup-free surfactant (Nohead FC6-HC4) produced data that implied the formation of W/CO2 microemulsions (MEs) at a particular pressure (P)... -
Interlayer structure and bonding in primary amine intercalated clays under oi...
Organo-amine and ammonium compounds are particularly useful for the oil and gas exploration sector as they aid in the inhibition of swelling in clay mineral-rich shale... -
Understanding the Earth's Core-Mantle Boundary: The High-Pressure Behaviour o...
The physical properties of the post-perovskite phase of MgSiO3 control the dynamics of the lower thermal boundary layer of the Earth¿s mantle but many of these properties cannot... -
Inelastic Neutron Scattering Studies of Gas-Loaded Porous MOFs
We request 13 days on TOSCA to study the interaction of adsorbed gas molecules (NO2, NO, N2O, C2H2, C2H4, and C2H6) within one metal-carboxylate porous MOF material. This... -
Local structure of a barocaloric framework material
Barocaloric materials, in which a large isothermal entropy change is associated with a pressure-induced phase transition, offer an alternative to vapour-compression techniques... -
Effect of Composition on Local Environment of Sulphate in Silicate Glasses
We will study the effects of changes in composition and structure of alkali silicate and alkali-alkaline earth silicate glasses on its sulphate incorporation capacities. Total... -
Understanding the Earth's Core-Mantle Boundary: The High-Pressure Behaviour o...
Perovskite-structured MgSiO3 is the dominant mineral in the Earth's lower mantle. The transition between its perovskite (PV) and post-perovskite (PPV) polymorphs controls the... -
A series of robust metal-organic frameworks with exceptional capability for h...
We seek to develop new stable MOFs for practical gas separation and request 3 days on WISH to study the preferred binding sites of adsorbed gas molecules (CD4, C2D4 and C2D2)...
