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CO2-philic Low Surface Energy Surfactants for applications in Enhanced Oil Re...
In recent years, there has been an enormous interest in the study of surfactants for supercritical CO2 (scCO2). One important potential application of these materials is in... -
HC-polymer 3D-network conjugated by hydrocarbon-fluorocarbon core/shell aggre...
For the last two decades, many polymers have been tested to increase CO2 viscosity for enhanced oil recovery. Unfortunately, HC-polymers were found to be inactive for the... -
The formation of water-in-supercritical carbon dioxide microemulsions using q...
For twenty years scientists have been searching for surfactants able to solubilise water nano-domains in supercritical carbon dioxide, scCO2 (as water-in-scCO2 microemulsions,... -
Emulsification of Fire-fighting surfactants
The aim is to understand how the addition of a common hydrogenated/ deuterated oil affects the size of the self-assembled structure of three common industrial fluorocarbon (FC)... -
W/CO2 nanodispersions as an energy-saving nanoreactor separable by pressure a...
Recent studies implied an unusual headgroup (HG)-free, fluorocarbon (FC) surfactant Nohead FC6-HC4 to form stable, W/CO2 nanodispersions (W/C NDs). With the unusual surfactant... -
Optimizing surfactants for CO2
This experiment addresses an important, and still unresolved, question in the field CO2-philic surfactants: what is the minimum fluorine content necessary to obtain a CO2-philic... -
CO2 foams stabilized by W/CO2 interfacially active hydrocarbon surfactants an...
CO2 foams can be formed in water/carbon dioxide (W/CO2) mixtures with the aid of W/CO2 interfacially active hydrocarbon surfactants and surface treated silica nanoparticles... -
Rod-like micelles as CO2 fluid thickeners
Using LOQ, we have recently shown that self-assembly of fluoro-sulfocuccinate surfactants is indeed a viable approach to promote viscosity enhancement in liquid CO21 (Rod-like... -
A new approach to viscosity enhancement of oils and CO2
Due to the naturally low viscosity of liquid CO2 (0.1-1.0 cP pressure/temperature dependent) the CO2 is prone to ¿fingering¿, limiting the efficiency of CO2-EOR [1]. In order to... -
Exploring CO2-philic/ CO2-phobic amphiphiles, cross-linkers and HC-polymers f...
Over the last two decades, many polymers have been tested to increase CO2 viscosity for applications in enhanced oil recovery using CO2 (CO2-EOR). Unfortunately, conventional... -
Surfactant mixtures in CO2
Studies by the Bristol group, and elsewhere [1, 2], have shown that highly branched hydrocarbon chains is the key factor for generating effective non-fluorous CO2 philic... -
Micelles of highly branched surfactants at the design limit
Results from this experiment will help develop to design 21st century surfactants (better performance with lower environmental consequences) by gaining essential information on... -
Optimal fluorination and structure of triple-fluorocarbon-tail surfactants fo...
This proposal aims to explore optimal fluorine (F) content and chain architecture in triple-fluorocarbon (FC)-tail surfactants used as CO2-philic solubilizers for water-in-CO2... -
Probing the viability of water-in-CO2 microemulsions with Headgroup-free amph...
Recent SANS studies of an unusual headgroup-free surfactant (Nohead FC6-HC4) produced data that implied the formation of W/CO2 microemulsions (MEs) at a particular pressure (P)... -
Generation of 3D-networks by mixing inexpensive HC-polymers, amphiphiles, and...
For the last two decades, many polymers have been tested to increase CO2 viscosity for enhanced oil recovery using CO2 (CO2-EOR). Unfortunately, conventional HC-polymers were... -
Optimising graphene-philic surfactants as effective stabilizer for graphene p...
Graphene has been touted as a material of everything, but for all its promise it does have some drawbacks, especially in its poor dispersibility and instability in water (and... -
Measuring the bending rigidity of surfactant films in water-in-CO2 microemu...
This proposal aims to expand knowledge about water-in-CO2(w/c) microemulsions by studying the ¿bending rigidity¿ of surfactant films, which has been frequently tested on normal... -
Optimising chemical structure of CO2-philic hybrid surfactants for stabilisin...
The proposal aims to explore water-in-CO2 (w/c) microemulsions with very promising hybridCO2-philic surfactants. The surfactants have been systematically synthesised... -
Manipulation of the aggregate curvature in water/dense CO2 system
This proposal aims to investigate how the curvature of surfactant assemblies in water/dense CO2 systems can be tuned via the design and mixing of CO2-phillic surfactants. One... -
Are hydrotropes a unique class of solutes?
The aim is to improve understanding of solution properties and aggregation of hydrotropes and alkyl¿hydrotropes, and the relationship with common surfactants. Although they are...
