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Compressibility and Tilting of Polyhedra within Sr2NiMoO6 at High Pressure
Ordered double perovskites (also known as elpasolites) have the general formula A2BBO6 where A is generally a rare earth metal or alkaline earth metal and where B and B are... -
Phase diagram of a switchable dielectric framework near the critical point
The family of hybrid Prussian blue analogues includes many electroactive materials, where organic cations moving within the pores of the cyanide framework cause unusual and... -
Structural changes in pressure-amorphized THF-clathrates
Clathrate hydrates are crystalline compounds in which water forms a host with cages that enclose guest molecules. Clathrate hydrates occur widely in nature with guest such as... -
Single-crystal neutron diffraction study of sucrose at high pressure.
In the context of expanding the sample environments available for experiments on the SXD instrument, the Paris-Edinburgh press recently developed on PEARL offers the possibility... -
Correlated local structure distortions in the family of high-temperature supe...
This proposal follows from a short previous test experiment (RB 920345) aimed at understanding the nature of local structure distortions in YBa2Cu3O6.9 and their possible role... -
Phase transitions in melamine at high pressure
Melamine is a common organic molecule based on a six-sided ring; this unit typically connects with itself or other organic species to form layered crystal structures, which then... -
Local ordering in the pressure-induced order-disorder transition in ammonium ...
Ammonium bromide undergoes a pressure-induced order-disorder transition, where the disordered (plastic) phase is thought to consist of a random distribution of ammonium cations... -
The icy-moon analogue of MgSiO3-perovskite: MgSO4.9H2O a high-pressure study
Mg-sulfate 11-hydrate (meridianiite) is decomposed by pressure to form Mg-sulfate 9-hydrate + ice, a process that will occur in the mantles of large icy planetary bodies and... -
Thermodynamic Control of Isotopic Polymorphism
Co-crystals of 4-methylpyridine and pentachlorophenol (MP-PCP) exhibit the very unusual property of isotopic polymorphism, formation of different phases by samples differing... -
LOW DIMENSIONAL NETWORKS UNDER PRESSURE. IN-SITU DIFFRACTION MEASUREMENTS OF ...
Carbonate liquids are characterised by low temperature and low viscosity and play an important role in molten carbonate fuel cells, battery electrolytes and, surprisingly, in... -
Understanding of Competing Magnetic Processes in La0.7Sr0.3MnxFe1-xO3 Perovskite
The aim of this experiment is to complete the understanding of the complex nature of the structural and magnetic interactions in the La0.7Sr0.3Mn1-xFexO3 series of materials in... -
Modulation in Molecular Materials under Pressure
Modulation has been understood and used to explain physical properties in solid-state materials for many years. Molecular modulated structures relatively scarce, but due to... -
The phase stability of alpha-glycine at high pressure
Though the beta and gamma forms of the simplest amino acid, glycine, yield a variety of different phases on application of pressure, Raman data suggest that the most common... -
High pressure charge transitions in PbCoO3
PbCoO3 used to be the missing link in the PbMO3 perovskite series. PbCoO3 was recently synthesized by the Azuma group using high-pressure synthesis at 12 GPa. NPD at JPARC... -
High pressure charge transitions in PbCoO3
PbCoO3 used to be the missing link in the PbMO3 perovskite series. PbCoO3 was recently synthesized by the Azuma group using high-pressure synthesis at 12 GPa. NPD at JPARC... -
PT-phase diagram of ammonium bromide
Ammonium bromide is a fundamental ionic solid that finds practical use, industrially, as a highly-effective flame retardant and also as an intermediary source of bromide in... -
Comparison of the Compression Behaviour of BaSnO3 and Ba0.575Sr0.425SnO3
We propose to study the effect of pressure on the structure of the tetragonal Ba0.575Sr0.425SnO3, The behaviour will be compared to the compression of the cubic BaSnO3 (parent... -
High pressure structural study of BaD2
Simple hydrides are of scientific interest due to their suitability for storage of hydrogen in the solid state. These materials also display a wealth of interesting physics,... -
Low temperature, high pressure phase transition of the Improper Ferroelectric...
We have found that the 134-perovskite, HgMn7O12 (HgAMnA3MnB4O12) exhibits improper ferroelectric coupling due to an unusual orbital ordering of the manganese cations on both... -
High Pressure Phase Diagram of BaTiO3
Lead based ferroelectric perovskite structured materials are extensively used in industrial applications. However, as a result of the need for more environmentally friendly...
