A high pressure study of the novel hybrid improper ferroelectric HgMn7O12

DOI

We have recently discovered how a novel type of hybrid improper ferroelectricity can arise in the perovskite HgMn3Mn412. This ferroelectricity is driven by a highly unusual charge transfer and orbital ordering process that induces a polar grounds state. Interestingly, isoelectronic CaMn3Mn4O12 exhibits a different sequence of phase transitions with rather different orbital physics that does not directly lead to hybrid improper ferroelectricity. The present study seeks to use high pressure to tune through the differing orbital ordered phases of HgMn3Mn3O12 giving greater insight into the physical driving forces behind this novel kind of ferroelectricity. This will help us not only gain insight into how the unusual charge and orbital physics surrounding the ferroelectric state in HgMn7O12 arises, but will give us indications how it can be induced and controlled in other related systems.

Identifier
DOI https://doi.org/10.5286/ISIS.E.99687732
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/99687732
Provenance
Creator Dr Nicholas Funnell; Dr Mark Senn; Dr Wei-tin Chen; Dr Fernando Pomiro; Dr Anna Herlihy
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2018-11-22T10:00:00Z
Temporal Coverage End 2018-12-04T08:19:24Z