This table contains the 5th edition of the Roma-BZCAT catalog of blazars which contains coordinates and multi-frequency data of 3561 sources. It presents several relevant changes with respect to the past editions which are briefly described in the reference paper. The Roma-BZCAT catalog contains data on 3561 sources, about 30% more than in the 1st edition, which either confirmed blazars or exhibiting characteristics close to this type of sources. With respect to the previous editions, this new edition has relevant changes in the sources' classification. The authors emphasize that all the sources in the Roma-BZCAT have a detection in the radio band. Moreover, complete spectroscopic information is published and could be accessed by the authors for all of them, with the exception of BL Lac candidates. Consequently, peculiar sources such as the so called "radio quiet BL Lacs", which are reported in some other catalogs, are not included here because of possible contamination by hot stars and other extragalactic objects. In the 5th edition, the authors use a similar denomination for the blazars to that adopted in the previous editions. Each blazar is identified by a code, with 5BZ for all blazars, a fourth letter that specifies the type (B, G, Q or U), followed by the truncated equatorial coordinates (J2000). The authors introduced the edition number before the letters BZ to avoid possible confusion due to the fact that several sources changed their old names because of a newly adopted classification. The 5th edition contains 1151 BZB sources (92 of which are reported as candidates because their optical spectra could not be found in the literature), 1909 BZQ sources, 274 BZG sources, and 227 BZU objects. This database table was originally ingested by the HEASARC in September 2013, based on <a href="https://cdsarc.cds.unistra.fr/ftp/cats/J/A+A/495/691">CDS Catalog J/A+A/495/691</a> file bzcat4.dat. It was updated in March 2016, and it is now based on <a href="https://cdsarc.cds.unistra.fr/ftp/cats/VII/274">CDS Catalog VII/274</a> file bzcat5.dat. This is a service provided by NASA HEASARC .