uSR study of low temperature magnetism in Li NMC 811

DOI

LiNi0.8Mn0.1Co0.1O2 (Li NMC 811) is a next generation Li ion battery cathode material. We are investigating the magnetic properties of Li NMC 811 to track the changes in local ordering of the magnetic ions and changes in oxidation state as a function of electrochemical cycling. Here we focus on pristine Li NMC 811 which contains S=1/2 Ni3+, S=1 Ni2+, S=3/2 Mn4+ and S=0 Co3+. In addition it is prone to off-stoichiometry and Li/Ni site disorder due to which some Ni2+ spins occupy the Li+ layers. It is not possible to determine the nature of the magnetic ground state for such complex systems with multiple magnetic species from bulk magnetic susceptibility measurements alone. uSR is the ideal probe to study the local magnetism and we propose to carry out zero field and weak transverse field uSR measurements to investigate the sample-dependent nature of the magnetic ground state.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB2010092-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/109983547
Provenance
Creator Dr Innes McClelland; Miss Paromita Mukherjee; Dr Peter Baker; Dr Sian Dutton; Mrs Nicola Kelly; Miss Camilla Tacconis
Publisher ISIS Neutron and Muon Source
Publication Year 2023
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Natural Sciences; Physics
Temporal Coverage Begin 2020-03-07T08:30:00Z
Temporal Coverage End 2020-03-10T08:30:00Z