Influence of shear on polymer adsorption at solid / liquid interfaces

DOI

Lubricants contain a complex mixtures of polymers and base oils that must provide protection to moving surfaces with minimal energy loss due to friction or viscous drag. There is considerable interest in the relationship between bulk and interfacial properties of lubricants, especially under the extremes of pressure, temperature and shear rate are routinely found in engines. Here we propose a simple model system, based on polybutadiene and squalane, for which we have already established the phase behaviour under quiescent conditions. Interestingly, rheometry using a multi-pass rheometer indicates that phase separation may occur under moderate shear rates. We will use NR to determine surface segregation under quiescent conditions and under shear using a new setup on INTER. Results will give valueable insights into the modes of action and failure in model lubricants.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1810577-2
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/109729426
Provenance
Creator Dr Ophelie Squillace; Dr Rebecca Welbourn; Mr Colin Gibson; Dr Richard Thompson; Dr Andrew Smith; Mr Matthew Litwinowicz; Dr Benedicte Galmiche; Dr Stephen Boothroyd; Mr Ben Robertson; Dr James Hart; Mr Callum Bannister
Publisher ISIS Neutron and Muon Source
Publication Year 2023
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2020-02-27T08:30:00Z
Temporal Coverage End 2020-03-04T15:41:43Z