Models of the [FeFe]-hydrogenase active site: raising the symmetry

DOI

The [FeFe]-hydrogenase enzymes are some of the best catalysts know for generating hydrogen. We have an ongoing programme to understand how their chemistry works, and to replicate the core 'active site' of the enzyme. Building on previous work, here we will use a model with high symmetry to produce stronger signals than can be achieved using a more realistic mimic. This will help us to identify unique reactivity in our systems, and will enable us to build toward a greater understanding of the overall reaction scheme.

Identifier
DOI https://doi.org/10.5286/ISIS.E.98001977
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/98001977
Provenance
Creator Dr Joseph Wright; Dr Stephen Cottrell
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2018-09-18T08:00:00Z
Temporal Coverage End 2018-10-17T16:59:25Z