Electronic state of Co3+ in LaCoO3

DOI

We will search for spin-orbit transitions of the Co3+ ions in LaCoO3. The ground state is a non-magnetic singlet, but there continues to be a debate about the nature of the lowest excited levels, which could either be from the intermediate spin (S=1) or high spin (S=2) terms. We have calculated the neutron cross section based on a recently-published model and obtained predictions of electronic transitions which should be present in the neutron spectrum. We will measure the spectrum up to 500 meV at base temperature and room temperature. If we can measure these excitations then it will provide a direct and unambiguous resolution to a 50-year old problem.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24088944
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24088944
Provenance
Creator Professor Andrew Boothroyd; Mr Stephen Gaw; Dr Martin Rotter
Publisher ISIS Neutron and Muon Source
Publication Year 2015
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2012-03-29T13:33:10Z
Temporal Coverage End 2012-05-25T22:15:31Z