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Thermodynamic Control of Isotopic Polymorphism
Co-crystals of 4-methylpyridine and pentachlorophenol (MP-PCP) exhibit the very unusual property of isotopic polymorphism, formation of different phases by samples differing... -
Surfactant aggregation in magnetic ionic liquids
This proposal aims to explore aggregation behavior of common surfactants in magnetic ionic liquids (MILs) and to investigate the effect of a magnetic field on aggregate size,... -
Surface Active Carbene (Surfenes) Precursors and Complexes
Within the last decade N-heterocyclic carbene (NHC) ligands have been widely recognised for their numerous catalytic applications. However, despite their widespread use as... -
Emission Enhancing Micelles and Microemulsions for the Analytical Sciences
Nuclear power has played an important role in Britain¿s history and is set to play an equally important role in its future. We have recently established a network involving... -
Low field µSR studies of radiation chemistry and free radical reactions by no...
Microwave (MW) assisted chemical reactions are of interest as a green, energy efficient alternative to conventional thermal heating for chemical processes. MW irradiation... -
Temperature Variation of Stresses in a W-Cu Composite under Compressive Loading
The aim is to make in-situ measurements of the strains in both the tungsten matrix and the copper infiltrate in the mechanical testing machine on ENGIN-X. Mechanical tests will... -
Tuning micellar interfacial curvature in CO2 by small molecule additives
This proposal aims to explore co-surfactants, as additives with CO2-active surfactants, for elongating reversed micelles in dense CO2 by using high-pressure small-angle neutron... -
Close control over microemulsion stability using blended solvents
The aim of this proposal is to investigate a novel approach to phase separation in microemulsions using careful choice of organic solvents, and appropriate mixtures.... -
Organogels for applications in CO2
This proposal aims to explore organogel systems, like those recently decsribed1-3, but made from new CO2 philic surfactant-gelators. These have been synthesised to feature... -
Evolving microemulsions - tuning selectivity in oxidation reactions
We have begun to explore the synthesis, reactivity and physicochemical properties of a number of surface-active metal complexes, to devise a method for the catalytic... -
Doping Effects on Electronic Phase Separation in CaFe3O5
Our recent study of CaFe3O5 revealed a remarkable discovery of electronic phase separation, similar to examples widely reported in manganite perovskites. Electronic phase... -
Are hydrotropes a unique class of solutes?
The aim is to improve understanding of solution properties and aggregation of hydrotropes and alkyl¿hydrotropes, and the relationship with common surfactants. Although they are... -
Structural evolution - hydrotrope to surfactant
The aim is to improve understanding about combinations of normal surfactants and hydrotropes in aqueous systems. This is to support our recent work with but in non-aqueous... -
Investigation of Multiple-q states around the Quantum Critical Point of URu2S...
URu2Si2 has been examined intensively over the decades for the rich phase diagram including superconductivity, Hidden Order and multiple magnetic phases appearing around the... -
Manipulation of the aggregate curvature in water/dense CO2 system
This proposal aims to investigate how the curvature of surfactant assemblies in water/dense CO2 systems can be tuned via the design and mixing of CO2-phillic surfactants. One... -
Investigation of the effect of increased spin-orbit coupling on the performan...
We wish to perform PNR measurements on organic spin valve devices to assess the effect on the device performances of the spin relaxation mechanisms related to spin-orbit... -
Co-existing Hydro/Fluorcarbon Microemulsions for Lanathanide Emission Enhance...
Very recently (April) we undertook a SANS experiment (RB1110147) to probe the partitioning of metal-acac ligand complexes in complex microemulsion media. Our aim was to design a... -
Inverse Metallosurfactants and Metallomicroemulsions
Incorporation of d- or f-block metals into ligand systems that renders a metal complex surface active or drives its partitioning into surfactant phases enables the localisation... -
Polymer-induced critical pase separation
This proposal concerns a novel approach to phase separation in self-assembling colloidal systems. Microemulsions can be readily formulated to display critical-type phase... -
Gels in CO2
The proposal aims to explore different self-assembly structures in CO2 with the focus of developing viscosity modifiers for supercritical CO2 (sc-CO2). This is part of a...