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Unraveling Local Structure in Pseudocubic Perovskite Solid Solutions
Recently, several perovskite-like ceramic-oxide solid solutions featuring pseudocubic symmetry have been reported to exhibit technologically promising dielectric and... -
Structure-property relationship of perovskites ABO3 (A=La,Ca,Sr, B=Ni,Co,Fe,M...
Perovskites are used in many applications such as electrode materials in fuel cells or as catalysts e.g. in syngas conversion, CO oxidation, N2O decomposition, or... -
HC-polymer 3D-network conjugated by hydrocarbon-fluorocarbon core/shell aggre...
For the last two decades, many polymers have been tested to increase CO2 viscosity for enhanced oil recovery. Unfortunately, HC-polymers were found to be inactive for the... -
Metastable phase formation and memory effects in barium borate glasses.
BaB4O7 glass crystallises to different polymorphs of the same composition depending on the prior thermal history of the glass and the surface area of the sample. This indicates... -
IN-SITU NEUTRON DIFFRACTION STUDIES OF METAL-HYDRIDE HYDROGEN STORAGE MATERIALS
Hydrogen storage is considered to be one of the principal technological barriers in the transition towards a hydrogen-based economy. In this proposal, we plan to look at the key... -
Structures of Gel Precursors of Nanoporous Materials
Nanoporous zeolites are well-known materials with huge industrial and commercial application in important areas yet their crystallisation mechanism remains under great debate.... -
Structural evolution and negative thermal expansion of Sr2IrO4
Sr2IrO4 is an important material in condensed matter physics, displaying a novel Jeff=½ Mott insulating state and being a rare comparative system for understanding the high... -
Neutron diffraction study of local and mesoscopic disorder induced by La and ...
The accurate determination of the defect structure of rare earth (RE) doped ceria solid electrolytes is fundamental for the comprehension of oxygen diffusion and charge... -
Acceptor-doped BiFeO3: Oxide Ion Conduction and Possible Structural Disorder.
2 days of beamtime is requested on Polaris to study the defect structure of an oxide-ion conductor Bi1-xBaxFeO3-x/2. RT total neutron scattering studies on samples heat treated... -
Structures of Titanium Dioxide Nanomaterials using Neutron Total Scattering
We propose to examine the structure of anatase titanium dioxide (TiO2) obtained by different synthetic techniques (including hydrothermal and sol-gel) and of different particle... -
Structure of the lithium battery cathode Li2(Fe,Mn)SiO4
There is great interest in scaling up Li-ion batteries for use in electric vehicles, requiring cheap and safe cathodes. Li2FeSiO4 shows promising performance as a cathode but... -
The Structure of Lead Phosphomolybdate Glasses
Molybdenum containing glasses have many potential applications. However, there is little information available on the structural role of molybdenum in glasses, and the limited... -
P and Al substitutions in the lithium battery cathode Li2FeSiO4
There is great interest in scaling up Li-ion batteries for use in electric vehicles, requiring cheap and safe cathodes. Li2FeSiO4 shows promising performance as a cathode but... -
'Stabbing' or 'cut & thrust'? Texture analysis to distinguish usage of Bronze...
Defining when the practical use of Bronze Age swords changed from stabbing to cut-and-thrust weapons would have a huge impact on Bronze Age research. The change was accompanied... -
Neutron Total Scattering Investigation of LaCoxMn1-xO3 Perovskites
The perovskite structure with general formula ABX3 describes many hundreds (if not thousands) of materials. Many have interesting and technologically important properties. The... -
Investigating the Mechanism of Cooperative Melting in Metal-Organic Frameworks
Zeolitic imidazolate frameworks (ZIFs) are formed from inorganic nodes connected by organic ligands, and share structural features with zeolites. They have recently been... -
Framework flexibility and host-guest hydrogen bonding across the phases of a ...
Metal-organic perovskites offer many of the advantages of their ceramic analogues, with a range of exploitable functionality including ferroelectricity. Understanding the... -
Diffraction of potassium-intercalated graphitic nanofibres with hydrogen
Nanostructured carbons are promising precursors for a high-capacity reversible hydrogen storage material with fast kinetics, but the interaction of H2 with pure graphite is too... -
Neutron diffraction study of local and mesoscopic disorder induced by La and ...
The accurate determination of the defect structure of rare earth (RE) doped ceria solid electrolytes is fundamental for the comprehension of oxygen diffusion and charge... -
ToF ND investigation of Medieval double-edged swords
The European Medieval double-edged sword develops in the 11th century from the Viking Age sword. Already in the 10th century, some of the finest examples of the Ulfberht type of...