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Local structure of liquid gallium-iodine and gallium-indium
Liquid metal alloys, with liquidus temperatures close to room temperature, are a rapidly developing research area with novel applications in renewable energy, catalysis,... -
Define the crystal structures of lead-free ferroelectric, candidate multiferr...
We have a range of new structures in the lead-free ferroelectric, candidate multiferroic and SOFC cathode areas. The HRPD data will be used to define these new crystal... -
High-Temperature Neutron Diffraction of Thermoelectric Materials
We wish to investigate the origin of the promising thermoelectic performance of oxy-chalcogenides BiOCuQ (Q = S, Se, Te) and related phases. We wish to explore whether the low... -
In-situ studies of thermal electrochemical cells utilising transition metal s...
Thermal batteries are used in applications were high reliability is a key requirement. They can be stored for decades and activated in less than a second. Most contemporary... -
The adsorption of methyl proprionate on silica catalysts.
Commercial routes for the manufacture of methyl methacrylate monomer have recently been developed that involve the reaction of esters over modified silicas, which are amphoteric... -
Can we use the H-H stretch of adsorbed dihydrogen to characterise materials?
The use of the J 0-to-1 rotational transition of dihydrogen has been extensively used to characterise the state if hydrogen in and on materials. The disadvantage of studying the... -
Average structures of new functional oxides - HPRD
The proposal addresses the average structures of new lead-free ferroelectrics, low-temperature ionic conductors and mixed conductors which are candidate solid oxide fuel cell... -
Local cation ordering in bismuth yttrium ytterbium oxide solid electrolytes
Solid electrolytes based on Bi2O3 exhibit high conductivity at intermediate temperatures (300-600 deg C) and recent research has revealed the true potential of these materials... -
High-Temperature Crystal Structure of Aluminium-Substituted La(Sr)Ga(Mg)O3-d ...
Due to a high-oxide ion conductivity, strontium and magnesium co-substituted lanthanum gallate (LSGM) is considered as a potential electrolyte material for solid oxide fuel... -
The structures of PZT in its ¿rhombohedral¿ phases and their dependence on th...
In the piezoelectric ceramic material PbZrxTi1-xO3 (PZT) there is controversy about the structure of PZT at the Zr-rich end. This region has always been considered to be of... -
In-situ neutron diffraction and conductivity measurement for high proton cond...
Sr1-xBaxCe0.5Zr0.35Y0.1Sm0.05O3-&; (SrBCZYSm) where x = 0,0 - 0.9 are promising as intermediate temperature solid oxide fuel cell electrolyte. PXRD reveals that all of the... -
Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and... -
In-situ studies of amides with ammonia
The aim of this proposal is to determine that materials that are present in the ammoniation of amides. -
Local structure of liquid gallium-iodine and gallium-indium
Liquid metal alloys, with liquidus temperatures close to room temperature, are a rapidly developing research area with novel applications in renewable energy, catalysis,... -
In-situ neutron diffraction and conductivity measurement for high proton cond...
Sr1-xBaxCe0.5Zr0.35Y0.1Sm0.05O3-&; (SrBCZYSm) where x = 0,0 - 0.9 are promising as intermediate temperature solid oxide fuel cell electrolyte. PXRD reveals that all of the... -
In-situ study of structure-property relationships on proton conducting perovs...
Significant research has been given towards synthesis and characterisation of electrolyte materials with high proton conductivity for intermediate temperature range (200-600°C)... -
Programme Access Rosseinsky
This dataset has no description
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Diffusion studies using methane as a probe molecule to investigate the methan...
Methanol-to-Hydrocarbons (MTH) is an important industrial reaction. It is thought to work through a 'hydrocarbon pool' mechanism where the hydrocarbons retained within the... -
Defect Structure in Lead Doped Bismuth Yttrates
Stabilised bismuth oxides are of interest as intermediate temperature solid electrolytes for a variety of electrochemical device applications. Lead doping into bismuth yttrate... -
Phase Transitions in Pb/Y di-substituted Bi2O3 Based Electrolytes
There has been recent interest in the use of cermets based on stabilised delta bismuth oxide based solid electrolytes as cathodes in solid oxide fuel cells. It has been shown...
