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Self-assembly in biosurfactants and biosurfactant / surfactant mixtures
This proposal is part of a new project which is a collaboration between Oxford, Newcastle, Ulster, and Unilever on the development of sustainable laundry detergents, using... -
Understanding anaesthetics: Ethanol partitioning into lipid membranes, effect...
Ethanol plays an important role in the human metabolism. It is in particular known to act as a drug enhancer by increasing trans-membrane permeability, and as an anesthetic.... -
Multilayering of Methyl Ester Sulphonates at the Air-Aqueous Interface
Surfactants usually form a single layer of molecules at the surface of water. We have shown, surprisingly, that under certain conditions more than one layer may form. When this... -
Investigating the Mechanism of Cooperative Melting in Metal-Organic Frameworks
Zeolitic imidazolate frameworks (ZIFs) are formed from inorganic nodes connected by organic ligands, and share structural features with zeolites. They have recently been... -
Effect of temperature on the structure of model wax films as studied by neutr...
Cuticular wax films protect plants by mediating water and nutrient transport from the environment. Surfactant is a key ingredient in agrisprays that can promote the uptake of... -
On the peculiarities of the structure of particle stabilised foam
Many formulated products pass through or end up as foams, comprising immiscible millimeter sized bubbles dispersed into an aqueous continuous phase. Frequently, surfactants or... -
Surface multilayer structures in hydrophobin-Tween mixtures
Increased environmental pressures and awareness is promoting a major drive towards an increased use of biosurfactants to produce more biosustainable and biodegradable consumer... -
Surface adsorption of short peptide surfactants
Short peptide sequences consisting of hydrophobic and hydrophilic amino acid units are capable of self-assembly to lead to interfacial adsorption and solution nano-aggregation.... -
Micellar modifiers for CO2
This proposal focuses on a new approach to the formation of rod-like micelles in supercritical CO2 (scCO2). Recent successful high-pressure SANS (HP-SANS) results have shown for... -
Confinement of Liquids within an Anodic Alumina Support
The structure of liquids in confined geometries is of significant interest to many diverse areas, for instance chemical catalysis (liquid-phase reactions inside porous... -
Competitive adsorption of Fatty acid, Phosphoric acid and Sulphonic acid salt...
This proposal presents a comparative study of the adsorption of three key chemical groups onto an important technological substrate, viz. fatty acid salt (Sodium hexanoate),... -
Controlling diblock co-polymer morphologies via selective solvent annealing
Diblock co-polymers consist of two polymer chains with different chemical properties tied together at a central linking block. The interactions between the two blocks result in... -
Proton Zero Point Energy Effects on the Folding of Proteins
Earlier experiment at ISIS have shown that water responds to the distortion of the hydrogen bond network by delocalizing some of the protons in the vicinity of the defects. That... -
Structure of chain-grafted silica nanoparticles
The aim of the proposed experiment is to carry out a series of SANS measurements on chain-grafted silica nanoparticles prepared in our laboratory. In this experiment we plan to... -
Understanding the nature of perfume / surfactant interactions at interfaces
This proposal is part of a funded (CASE) project, aimed at understanding the delivery of benefit actives (perfumes) to interfaces and the development of new self-assembled... -
Competitive adsorption in hydrophobin-surfactant mixtures
Hydrophobins are small compact secreted fungal proteins which are strongly surface active and adhere to both hydrophobic and hydrophilic surfaces. Their strong surface activity... -
Exchange kinetics of complex coacervates core micelles
Coacervates have been studied for a long time for their unusual properties: they are dense networks of charged polymers that are soluble in water. Instead of flocculating when... -
DPPC bilayer oxidation by aqueous singlet oxygen
The oxidation of membrane lipids by reactive Oxygen Species, ROS, is implicated in cell apoptosis, cancer and ageing. We have performed preliminary experiments studying the... -
Is H-bonding the source of large heats of fusion in guanidinium based thermal...
The organic salt guanidinium mesylate [Gdm][CH3SO3] is a promising phase change material for thermal energy storage applications. It has melting point Tm = 208 °C, and... -
Structure of Colloidal Crystals Near a Solid Surface
The structure of colloidal crystals (dispersions of particles that spontaneously order in a regular array) is known to be influenced by solid boundaries. However there are few...
