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Local cation ordering in bismuth yttrium ytterbium oxide solid electrolytes
Solid electrolytes based on Bi2O3 exhibit high conductivity at intermediate temperatures (300-600 deg C) and recent research has revealed the true potential of these materials... -
Neutron reflectivity study of the effect of thermal annealing on the morpholo...
This projects aims to contribute to a better understanding of the relationship between processing conditions, active layer morphology and device performance in polymer solar... -
ENERGY HARVESTING: STUDY OF PHASE DIAGRAMS OF BINARY AND TERNARY MIXTURES BY ...
The proposal regards new low freezing transfer fluids materials for Solar Plants, which are currently a field of the highest interest. In general, mixtures commonly employed as... -
The adsorption of methyl proprionate on silica catalysts.
Commercial routes for the manufacture of methyl methacrylate monomer have recently been developed that involve the reaction of esters over modified silicas, which are amphoteric... -
Dynamics of poly-acrylonitrile in polymer-layered silicate micro-objects
We propose to measure vibrational spectra from poly-acrylonitrile confined in nanoporous silica matrixes. Polymers confined in silica have recently been the subject of great... -
In-situ studies of thermal electrochemical cells utilising transition metal s...
Thermal batteries are used in applications were high reliability is a key requirement. They can be stored for decades and activated in less than a second. Most contemporary... -
In-Situ Studies of Electrochemically Enhanced Performance in Perovskite Elect...
Recent studies in our laboratory have shown that a range of A-site deficient perovskite oxides, with carefully tuned chemical compositions, exhibit excellent properties when... -
Hydrogen interaction with Zr-based amorphous thin films for potential hydroge...
Amorphous alloys are of particular interest due to their less susceptibility to hydrogen embrittlement and corrosion, superior mechanical properties and more importantly lower... -
High-Temperature Neutron Diffraction of Thermoelectric Materials
We wish to investigate the origin of the promising thermoelectic performance of oxy-chalcogenides BiOCuQ (Q = S, Se, Te) and related phases. We wish to explore whether the low... -
Structure and stoichiometry of boron carbides synthesised by microwave heating
A key focus in industrial processing is finding greener routes to well-established, high performance materials. Boron carbide is such a material, with excellent mechanical and... -
Define the crystal structures of lead-free ferroelectric, candidate multiferr...
We have a range of new structures in the lead-free ferroelectric, candidate multiferroic and SOFC cathode areas. The HRPD data will be used to define these new crystal... -
QENS Investigation of Proton Conduction Mechanism in Spark-Plasma-Sintered Pr...
Fuel cells exhibit high-energy efficiency and the only release is clean water when used with hydrogen. Proton ceramic fuel cells (PCFC) are from special interest because proton... -
In-Situ Studies of Electrochemically Enhanced Performance in Perovskite Elect...
Recent studies in our laboratory have shown that a range of A-site deficient perovskite oxides, with carefully tuned chemical compositions, exhibit excellent properties when... -
Phase Transitions and Orbital Ordering in SrRu1-xCuxO3.
This proposal seeks to establish the importance of orbital ordering on the stability of the tetragonal phase in Cu doped SrRiuO3. Orbital ordering is believed to be a... -
In-situ neutron powder diffraction studies of non-stoichiometry in Na battery...
We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium... -
Investigating the mechanisms for the in situ growth of metal oxide nanopartic...
Composites materials that combine the flexibility and mechanical robustness offered by polymers with the functionality displayed by metal oxide nanoparticles offer new insight... -
Crystallographic Basis for the High Temperature, 2D Invar Effect in Copper Gi...
We wish to study the gillespite-structured phase Ba0.5Sr0.5CuSi4O10 at high temperatures to determine the structural basis of the invar-like (zero thermal expansion) of the a-b... -
Ba3Mo1-xNb1+xO8.5-x/2 novel oxide ion conductor: Local structure and structur...
Oxide ion conductors are researched as potential electrolytes in solid oxide fuel cells (SOFCs). Yttria-stabilized zirconia is currently the most commonly used electrolyte in... -
Oxide Ion Disorder in Rhombohedral Bismuth Neodymium Oxide Electrolytes
Materials that exhibit high oxide ion conductivity are of interest with a view to their application in solid oxide fuel cells, gas sensors and gas separation membranes. A study... -
Short range static and thermal disorder in glasses and crystals
We seek to use the temperature-dependence of the neutron correlation function to investigate the extent of static disorder in glasses and crystals, and also to investigate the...
