Printing Green: Microalgae-based materials for 3D printing with light [data]

DOI

Microalgae have emerged as sustainable feedstocks due to their ability to fix CO2 during cultivation, rapid growth rates, and capability to produce a wide variety of metabolites. Several microalgae accumulate lipids in high concentrations, especially triglycerides, along with lipid-soluble, photoactive pigments such as chlorophylls and derivatives. Microalgae-derived triglycerides contain longer fatty acid chains with more double bonds on average than vegetable oils, allowing a higher degree of post-functionalization. Consequently, they are especially suitable as precursors for materials that can be used in 3D printing with light. Herein, we present the use of microalgae as “biofactories” to generate materials that can be further 3D printed in high resolution In this study two taxonomically different strains —Odontella aurita (BEA 0921B) and Tetraselmis striata (BEA 1102B)— are identified as suitable microalgae for our purpose. The extracts obtained from the microalgae (mainly triglycerides with chlorophyll derivatives) have been functionalized with photopolymerizable groups and used directly as printable materials (inks) without the need for additional photoinitiators. The fabrication of complex 3D microstructures with sub-micron resolution is demonstrated. Notably, the 3D printed materials show biocompatibility. Our findings open new possibilities for the next generation of sustainable, biobased, and biocompatible materials with great potential in life science applications.

Identifier
DOI https://doi.org/10.11588/data/KSMIGY
Related Identifier IsCitedBy https://doi.org/10.1002/adma.202402786
Metadata Access https://heidata.uni-heidelberg.de/oai?verb=GetRecord&metadataPrefix=oai_datacite&identifier=doi:10.11588/data/KSMIGY
Provenance
Creator Vazquez-Martel, Clara ORCID logo; Florido Martins, Lilliana ORCID logo; Genthner, Elisa; Almeida, Carlos ORCID logo; Martel Quintana, Antera ORCID logo; Bastmeyer, Martin ORCID logo; Gómez Pinchetti, Juan Luis ORCID logo; Blasco, Eva ORCID logo
Publisher heiDATA
Contributor Vazquez-Martel, Clara
Publication Year 2024
Funding Reference Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) via the Excellence Cluster “3D Matter Made to Order” EXC-2082/1-390761711 ; Carl Zeiss Foundation Carl-Zeiss-Foundation-Focus@HEiKA ; Fonds der Chemischen Industrie Kekulé Fellowship ; European Territorial Cooperation Program PCT-MAC 2014-202 REBECA-CCT (MAC2/1.1.B/269)
Rights CC BY 4.0; info:eu-repo/semantics/openAccess; http://creativecommons.org/licenses/by/4.0
OpenAccess true
Contact Vazquez-Martel, Clara (Institute of Molecular Systems Engineering and Advanced Materials (IMSEAM), Heidelberg University Im Neuenheimer Feld 225, 69120 Heidelberg, Germany)
Representation
Resource Type Dataset
Format application/zip; text/plain
Size 1847324865; 46696; 441388; 4211173; 1078; 14547
Version 1.0
Discipline Chemistry; Natural Sciences