Pore-water and solid-phase chemistry for sediment cores with turbidites from the Black Sea

DOI

During the PhOxy cruise with R/V Pelagia in June 2013, sediments were collected with a multicorer in the eastern part of the Black Sea. The aim was to determine the geochemical siganture of sediments on the shelf and in the deep basin, and potentially track chemical changes to sediments that are transported into the sulfidic deep basin by turbidity currents. Sediment cores were cut at vertical resolution of 0.5-2.0 cm and the pore-water and solid-phase were separated by centrifugation. After filtration of the pore-water over 0.45 micrometer filter membranes, dissolved inorganic carbon (DIC), Fe, P, Mn, N (ammonium, nitrite, nitrate) and S (sulfate, sulfide) were measured in various sub-samples. After freeze drying and grinding, sub-samples of dry sediment were taken and solid-phase org-C, Al, Ca, Fe, Mn, Mo, P and S were determined by decalcification and combustion (org-C) or ICP-MS analysis of acid digest (other elements). Furthermore, various solid-phase Fe and P pools were determined using sequential chemical extraction protocols. From a second core, 10-mL wet sediment samples were taken at 5-cm resolution from a multicore with pre-drilled holes and transferred into glass vials with gas-tight, crimp-sealed rubber stoppers filled with N2-purged saturated NaCl (no headspace). Later, a N2 headspace was injected and the headspace was analyzed for CH4 by gas chromatography with a flame ionization detector (GC-FID, Thermo Finnigan).

Identifier
DOI https://doi.org/10.1594/PANGAEA.933151
Related Identifier https://doi.org/10.1016/j.marchem.2019.01.001
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.933151
Provenance
Creator Kraal, Peter ORCID logo; Yücel, Mustafa (ORCID: 0000-0002-7478-902X); Slomp, Caroline P ORCID logo
Publisher PANGAEA
Publication Year 2021
Funding Reference Dutch Research Council https://doi.org/10.13039/501100003246 Crossref Funder ID 822.01013 https://www.nwo.nl/en/projects/82201013-0 Coupled cycling of phosphorus, iron and manganese in the Black Sea: elucidating the controls on mineral formation and burial in an anoxic basin; Dutch Research Council https://doi.org/10.13039/501100003246 Crossref Funder ID 863.14.014 https://www.nwo.nl/en/projects/86314014 Iron mineral transformations and preservation: Effects of eutrophication-driven changes in sediment geochemistry; Dutch Research Council https://doi.org/10.13039/501100003246 Crossref Funder ID 865.13.005 Response of the Iron Biogeochemical Cycle on Continental Shelves to Seawater Deoxygenation; European Research Council https://doi.org/10.13039/501100000781 Crossref Funder ID 278364 Phosphorus dynamics in low-oxygen marine systems: quantifying the nutrient-climate connection in Earth's past, present and future (PHOXY)
Rights Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Representation
Resource Type Bundled Publication of Datasets; Collection
Format application/zip
Size 2 datasets
Discipline Earth System Research
Spatial Coverage (29.278W, 41.463S, 30.678E, 43.735N)
Temporal Coverage Begin 2013-06-08T00:00:00Z
Temporal Coverage End 2013-06-21T00:00:00Z