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Monitoring crystallisation of Y3Al5O12 (YAG) under supercritical conditions u...
This proposal seeks 2 days on POLARIS in order to study hydrothermal chemical syntheses of yttrium aluminium garnet, Y3Al5O12 (YAG) in supercritical water using the... -
In-situ reaction of lithium amide or imide with manganese(IV) oxide
We request 3 days beam time on POLARIS for in-situ powder diffraction studies of the reactions of lithium amide or lithium imide with manganese(IV) oxide under flowing argon or... -
Formation and ammonia decomposition behaviour of lithium nitride hydride
Ammonia is seen as a key part of the transition to a sustainable energy economy, but needs decomposition catalysts to release its stored hydrogen. Lithium nitride-hydride... -
Simltaneous dielectric spectroscopy and neutron diffraction
We have constructed a novel microwave frequency resonator that can sit within the GEM and POLARIS diffractometers and will allow us to simultaneously collect diffraction and... -
Improved detection limit of hydrogen in materials using VESUVIO
The detection of hydrogen content in bulk media is a challenging task. Several techniques aiming at measuring the amount of hydrogen require disruption or erosion of the sample.... -
Sensing SO2 in Robust Porous MOF Materials via Simultaneous Microwave Dielect...
We seek to develop new MOFs for sensing and removal of toxic gases (e.g., SO2) and request 4 days on POLARIS to study the structural binding details and dielectric data... -
In-situ Thermoelectric Measurements of Copper Iron Sulphides
Thermoelectric devices are capable of converting thermal energy directly into electrical energy. Large-scale applications of the technology requires materials that are composed... -
The solvation of ammonia borane by diglyme
Ammonia borane (AB) is arguably the most promising hydrogen storage material for use in clean, green fuel applications. Simple heating of AB produces hydrogen that can be used... -
Configurational and displacive disorder in the cubic NTE material Cd(CN)2
Cubic cadmium(II) cyanide shows the most pronounced isotropic NTE effect known, with behaviour more than twice as extreme as that of better known materials such as ZrW2O8. This... -
Low-energy magnetic excitations in the superconducting state of Sr2RuO4: open...
We propose to study the magnetic fluctuations of the unconventional superconductor Sr2RuO4 in the superconducting state extending our previous experiments on a cold triple-axis... -
In-Situ Studies of Alternative Mobile-Ions for High-Temperature Thermal Batte...
Whilst rechargeable batteries continue to take over the consumer electronics market, they are unsuitable to replace specific battery technologies, such as the thermal battery,... -
Test of a New Supercritical In-Situ Hydrothermal Cell
The objectives of this proposal is to seek 2 days on POLARIS in order to test and complete a full commissioning of the latest design of our prototype in-situ reaction cell for... -
Investigating the formation of novel mixed amide-imide complexes and understa...
Inexpensive light-metal amides are among the most highly active and effective ammonia decomposition catalysts at modest temperatures and are likely to surpass the performance of... -
Structural determination of non-stoichiomentric phases Li2+yND for 0<y<1
In a series of in situ neutron diffraction measurements from deuterium up-take in Li3N, the present authors have identified a novel non-stoichiometric 'quasi-imide' of... -
In-situ studies of alkaline earth nitride deuterides
Heavy alkaline earth nitride hydrides (AE2NH, with AE = Ca and Ba) are of interest due to their potential suitability as electrolyte materials in a variety of electrochemical... -
Investigation of a frustrated quantum magnet with novel interaction scheme
SrCuTe2O6 consists of a 3-dimensional arrangement of spin-1/2 Cu ions that are coupled into network of isolated triangles,a highly frustrated hyperkagome lattice consisting of... -
Influence of the electric dipole moment of gas molecules on the gate-opening ...
The aim of this proposal is to study the condensation transitions of polar gas molecules in nanoporous flexible materials by means of wide Q-range neutron diffraction. An... -
Simultaneous Microwave Dielectric Spectroscopy and Neutron Diffraction Measur...
Ammonia has been proposed as a high density chemical energy-storage media, which can be safely and reversible stored within low cost saline halides. Here we propose to extend... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
Building a comprehensive understanding of cation ordering in the commercial c...
The objective of the proposed experiment is to develop an understanding of the Li/Ni/Mn ordering in a commercially relevant lithium ion battery positive electrode,...