Contents of metal cations exchange capacity of ore minerals in ferromanganese micronodules from the Atlantic, Indian and Pacific Oceans

DOI

Results of experimental studies of ion exchange properties of manganese and iron minerals in micronodules from diverse bioproductive zones of the World Ocean were considered. It was found that sorption behavior of these minerals was similar to that of ore minerals from ferromanganese nodules and low-temperature hydrothermal crusts. The exchange complex of minerals in the micronodules includes the major (Na+, K+, Ca2+, Mg2+, and Mn2+) and subordinate (Ni2+, Cu2+, Co2+, Pb2+, and others) cations. Reactivity of theses cations increases from Pb2+ and Co2+ to Na+ and Ca**2+. Exchange capacity of micronodule minerals increases from alkali to heavy metal cations. Capacity of iron and manganese minerals in oceanic micronodules increases in the following series: goethite < goethite + birnessite < todorokite + asbolane-buserite + birnessite < asbolane-buserite + birnessite < birnessite + asbolane-buserite < birnessite + vernadite ~= Fe-vernadite + Mn-feroxyhyte. Obtained data supplement available information on ion exchange properties of oceanic ferromanganese sediments and refine the role of sorption processes in redistribution of metal cations at the bottom water - sediment interface during micronodule formation and growth.

Supplement to: Novikov, Georgy V; Sval'nov, Vyacheslav N; Bogdanova, Olga Yu; Sivtsov, Alexander V (2010): Ion exchange properties of manganese and iron minerals in oceanic micronodules. Translated from Litologiya i Poleznye Iskopaemye, 2010, 5, 461-476, Lithology and Mineral Resources, 45(5), 410-424

Identifier
DOI https://doi.org/10.1594/PANGAEA.788052
Related Identifier https://doi.org/10.1134/S0024490210050020
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.788052
Provenance
Creator Novikov, Georgy V; Sval'nov, Vyacheslav N; Bogdanova, Olga Yu; Sivtsov, Alexander V
Publisher PANGAEA
Publication Year 2010
Rights Creative Commons Attribution 3.0 Unported; https://creativecommons.org/licenses/by/3.0/
OpenAccess true
Representation
Language English
Resource Type Supplementary Publication Series of Datasets; Collection
Format application/zip
Size 7 datasets
Discipline Earth System Research
Spatial Coverage (-140.103W, -16.567S, 90.192E, 44.992N)
Temporal Coverage Begin 1984-01-02T00:00:00Z
Temporal Coverage End 1984-01-08T00:00:00Z